ČERNÁK, J., J. PAHÁROVÁ, Zdirad ŽÁK and Jaromír MAREK. CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS. In 223rd ACS (=American Chemical Society) National Meeting. WASHINGTON: American Chemical Society, 2002, p. 063-63. ISSN:0065-7727.
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Basic information
Original name CYANOCOMPLEXES WITH MULTI-N-DONOR LIGANDS
Authors ČERNÁK, J. (703 Slovakia), J. PAHÁROVÁ (703 Slovakia), Zdirad ŽÁK (203 Czech Republic, guarantor) and Jaromír MAREK (203 Czech Republic).
Edition WASHINGTON, 223rd ACS (=American Chemical Society) National Meeting, p. 063-63, 2002.
Publisher American Chemical Society
Other information
Original language English
Type of outcome Proceedings paper
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United States of America
Confidentiality degree is not subject to a state or trade secret
RIV identification code RIV/00216224:14310/02:00006304
Organization unit Faculty of Science
ISBN ISSN:0065-7727
UT WoS 000176296800064
Keywords in English structure; cyanocomplex
Tags cyanocomplex, structure
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 21/5/2003 10:24.
Abstract
Cyanocomplexes containing bridging cyano ligands are attractive group of compounds as they may serve as models for the study of various physical phenomena associated with magnetism.Systems with various dimensionalities can be constructed using the 'brick and mortar' method. The dimensionality of the formed system can be controlled by a suitable choice of N-donor ligands coordinated to the cationic central atom (brick).The linking of the complex cations is made possible by the cyanocomplex anions (mortar). In search for new low-dimensional systems we have used the multi-N donor ligands dien (dien=N-(2-aminoethyl)-1,2-etylenediamine)and aepn (aepn=N-(2-aminoethyl)- 1,3-propanediamine). Several new tetracyanonickellate compounds were prepared and characterized by X-ray diffraction,and the resulting materials include oligonuclear and low-dimensional structures.
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MSM 143100011, plan (intention)Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles
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