Synthesis, characterisation and extraction behaviour of
calix[4]arene-based phosponic acids

J 2002

Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids

JUREČKA, Petr, Pavel VOJTÍŠEK, Karel NOVOTNÝ, Jan ROHOVEC, Ivan LUKEŠ et. al.

Basic information

Original name

Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids

Authors

JUREČKA, Petr (203 Czech Republic, guarantor), Pavel VOJTÍŠEK (203 Czech Republic), Karel NOVOTNÝ (203 Czech Republic), Jan ROHOVEC (203 Czech Republic) and Ivan LUKEŠ (203 Czech Republic)

Edition

Journal of the chemical society. Perkin transactions II, Physical organic chemistry, London, Chemical society, 2002, 1472-779X

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10406 Analytical chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

Impact factor

Impact factor: 1.911

RIV identification code

RIV/00216224:14310/02:00006329

Organization unit

Faculty of Science

UT WoS

000176467400025

Keywords in English

synthesis; extraction agent; calix[4]arene

Abstract

V originále

Three new bis(phosponic) acids were prepared by derivatization of p-tert-butylcalix[4]arene on the lower rim by -(CH2)x-PO3H2 groups and were fully characterized by NMR spectroscopy; some of them were further investigated by X-ray analysis. The compounds obtained were tested as extractants for La3+, Eu3+, Yb3+ and Th4+ in 0.1 - 1 M HNO3. Structural details of the complex HLn(H2L1)2 where Ln = Y, La, Eu were elucidated by NMR techniques in solution. The extraction efficiencies decrease with increasing length of the CH2 spacer; the dependence is not monotonic, and an extraordinary selectivity was observed for Yb. The extraction efficiency of Ln3+ for all of the ligands studied increased significantly with decreasing ionic radius.

Links

MSM 143100003, plan (intention)

Name: Studium plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek

Investor: Ministry of Education, Youth and Sports of the CR, Study of plasmachemical reactions in non-isothermic low pressure plasma and its interaction with the surface of solid substrates

Citovat

JUREČKA, Petr, Pavel VOJTÍŠEK, Karel NOVOTNÝ, Jan ROHOVEC and Ivan LUKEŠ. Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids. Journal of the chemical society. Perkin transactions II, Physical organic chemistry. London: Chemical society, 2002, vol. 2002, No 7, p. 1370-1377. ISSN 1472-779X.

@article{405001,
   author = {Jurečka, Petr and Vojtíšek, Pavel and Novotný, Karel and Rohovec, Jan and Lukeš, Ivan},
   article_location = {London},
   article_number = {7},
   keywords = {synthesis; extraction agent; calix[4]arene},
   language = {eng},
   issn = {1472-779X},
   journal = {Journal of the chemical society. Perkin transactions II, Physical organic chemistry},
   title = {Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids},
   url = {http://www.rsc.org/CFmuscat/intermediate_abstract.cfm?FURL=/ej/P2/2002/b105489a.PDF},
   volume = {2002},
   year = {2002}
}

TY  - JOUR
ID  - 405001
AU  - Jurečka, Petr - Vojtíšek, Pavel - Novotný, Karel - Rohovec, Jan - Lukeš, Ivan
PY  - 2002
TI  - Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids
JF  - Journal of the chemical society. Perkin transactions II, Physical organic chemistry
VL  - 2002
IS  - 7
SP  - 1370
EP  - 1370
PB  - Chemical society
SN  - 1472779X
KW  - synthesis
KW  - extraction agent
KW  - calix[4]arene
UR  - http://www.rsc.org/CFmuscat/intermediate_abstract.cfm?FURL=/ej/P2/2002/b105489a.PDF
N2  - Three new bis(phosponic) acids were prepared by derivatization of p-tert-butylcalix[4]arene on the lower rim by -(CH2)x-PO3H2 groups and were fully characterized by NMR spectroscopy; some of them were further investigated by X-ray analysis. The compounds obtained were tested as extractants for La3+, Eu3+, Yb3+ and Th4+ in 0.1 - 1 M HNO3. Structural details of the complex HLn(H2L1)2 where Ln = Y, La, Eu were elucidated by NMR techniques in solution. The extraction efficiencies decrease with increasing length of the CH2 spacer; the dependence is not monotonic, and an extraordinary selectivity was observed for Yb. The extraction efficiency of Ln3+ for all of the ligands studied increased significantly with decreasing ionic radius.
ER  -

JUREČKA, Petr, Pavel VOJTÍŠEK, Karel NOVOTNÝ, Jan ROHOVEC and Ivan LUKEŠ. Synthesis, characterisation and extraction behaviour of calix[4]arene-based phosponic acids. \textit{Journal of the chemical society. Perkin transactions II, Physical organic chemistry}. London: Chemical society, 2002, vol.~2002, No~7, p.~1370-1377. ISSN~1472-779X.

Detailed Information on Publication Record