Detailed Information on Publication Record
2002
Adamantane-Like Aluminum Amide-Phosphate from Alumazene
PINKAS, Jiří, Jiří LÖBL, Dalibor DASTYCH, Marek NEČAS, Herbert W. ROESKY et. al.Basic information
Original name
Adamantane-Like Aluminum Amide-Phosphate from Alumazene
Authors
PINKAS, Jiří (203 Czech Republic, guarantor), Jiří LÖBL (203 Czech Republic), Dalibor DASTYCH (203 Czech Republic), Marek NEČAS (203 Czech Republic) and Herbert W. ROESKY (276 Germany)
Edition
Inorg. Chem. Spojené státy americké, American Chemical Society, Washington DC, 2002, 0020-1669
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 2.950
RIV identification code
RIV/00216224:14310/02:00007041
Organization unit
Faculty of Science
UT WoS
000179797700046
Keywords in English
alumazene; adamantane; phosphates; iminoalanes
Tags
Změněno: 31/5/2009 22:21, prof. RNDr. Jiří Pinkas, Ph.D.
Abstract
V originále
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)2C6H3NAlMe]3 (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)2C6H3N]3{Al[OP(OSiMe3)3]}2(O3POSiMe3) (3). Compound 3 was characterized by analytical and spectroscopic methods and its molecular structure was established by a single-crystal X-ray diffraction experiment. Moreover, trialkyl and triaryl phosphates, and dialkyl phosphonates react with 1 at elevated temperature to afford an intractable mixture of products. The reaction of phosphonic acids with 1 proceeds under decomposition to yield 2,6-diisopropylaniline and aluminophosphonates.
Links
| GA203/01/1533, research and development project |
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