PINKAS, Jiří, Jiří LÖBL, Dalibor DASTYCH, Marek NEČAS and Herbert W. ROESKY. Adamantane-Like Aluminum Amide-Phosphate from Alumazene. Inorg. Chem. Spojené státy americké: American Chemical Society, Washington DC, 2002, vol. 41, No 25, p. 6914-6918. ISSN 0020-1669. |
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@article{407651, author = {Pinkas, Jiří and Löbl, Jiří and Dastych, Dalibor and Nečas, Marek and Roesky, Herbert W.}, article_location = {Spojené státy americké}, article_number = {25}, keywords = {alumazene; adamantane; phosphates; iminoalanes}, language = {eng}, issn = {0020-1669}, journal = {Inorg. Chem.}, title = {Adamantane-Like Aluminum Amide-Phosphate from Alumazene}, volume = {41}, year = {2002} }
TY - JOUR ID - 407651 AU - Pinkas, Jiří - Löbl, Jiří - Dastych, Dalibor - Nečas, Marek - Roesky, Herbert W. PY - 2002 TI - Adamantane-Like Aluminum Amide-Phosphate from Alumazene JF - Inorg. Chem. VL - 41 IS - 25 SP - 6914 EP - 6914 PB - American Chemical Society, Washington DC SN - 00201669 KW - alumazene KW - adamantane KW - phosphates KW - iminoalanes N2 - A dealkylsilylation reaction between alumazene [2,6-(i-Pr)2C6H3NAlMe]3 (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)2C6H3N]3{Al[OP(OSiMe3)3]}2(O3POSiMe3) (3). Compound 3 was characterized by analytical and spectroscopic methods and its molecular structure was established by a single-crystal X-ray diffraction experiment. Moreover, trialkyl and triaryl phosphates, and dialkyl phosphonates react with 1 at elevated temperature to afford an intractable mixture of products. The reaction of phosphonic acids with 1 proceeds under decomposition to yield 2,6-diisopropylaniline and aluminophosphonates. ER -
PINKAS, Jiří, Jiří LÖBL, Dalibor DASTYCH, Marek NEČAS and Herbert W. ROESKY. Adamantane-Like Aluminum Amide-Phosphate from Alumazene. \textit{Inorg. Chem.}. Spojené státy americké: American Chemical Society, Washington DC, 2002, vol.~41, No~25, p.~6914-6918. ISSN~0020-1669.
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