D 2002

Preconcentration of Divalent Metal Ions for Flame AAS by Donnan Dialysis with Nafion Capillary Membrane.

NOVOTNÝ, Karel and Josef KOMÁREK

Basic information

Original name

Preconcentration of Divalent Metal Ions for Flame AAS by Donnan Dialysis with Nafion Capillary Membrane.

Edition

Košice, Slovakia, XVIth Slovak Spectroscopic Conference. Book of abstracts. p. 74-74, 2002

Publisher

Technical University of Košice

Other information

Language

English

Type of outcome

Proceedings paper

Field of Study

10406 Analytical chemistry

Country of publisher

Slovakia

Confidentiality degree

is not subject to a state or trade secret

Organization unit

Faculty of Science

Keywords in English

preconcentration; flame AAS; Donnan dialysis; Nafion membrane
Changed: 5/6/2003 15:44, prof. RNDr. Josef Komárek, DrSc.

Abstract

V originále

A preconcentration system based on Donnan dialysis with a capillary cation exchange Nafion membrane was developed. The (hydrated) divalent metal ions were preconcentrated from sample (donor) solution to acceptor solution prior to determination by flame AAS. Under optimal conditions of dialysis the enrichment factor (EF) of 106 with RSD of 2% for Cu(II) was reached. The EFs for Cd(II), Co(II), Ni(II) and Zn(II) were found to be similar to that for Cu(II).

Links

MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles