The Reaction of Selenium Trioxide with 1,4-Dioxane

D 2002

The Reaction of Selenium Trioxide with 1,4-Dioxane

RICHTERA, Lukáš and Jiří TOUŽÍN

Basic information

Original name

The Reaction of Selenium Trioxide with 1,4-Dioxane

Authors

RICHTERA, Lukáš (203 Czech Republic) and Jiří TOUŽÍN (203 Czech Republic, guarantor)

Edition

Brno, Sborník příspěvků IV. seminář Pokroky v anorganické chemii, p. 56-57, 2002

Publisher

Masarykova univerzita v Brně

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/02:00007322

Organization unit

Faculty of Science

ISBN

80-210-2951-X

Keywords in English

DA-complex; Selenium trioxide; 1;4-Dioxane; Crystal structure; Raman spectra

Abstract

V originále

In effort to investigate molecular structures and spectral properties of the selenium trioxide adducts with organic oxygen donor we decided to verify the preparation of the selenium trioxide adducts with 1,4-dioxane. In this reaction was not possible to eliminate reduction of Se(VI) to Se completely due to high melting point of 1,4-dioxane. A white precipitate containing Se(VI) was formed as selenium trioxide dissolved. The Raman spectrum of this product differs substantially from spectra of other donor-acceptor compounds. A glass-like solid was isolated after the solvent removal under vacuum from the filtrate. Sublimation of this glass-like material at 50 cent. deg. under vacuum gave a small amount of cyclic ester C2H4O4Se. Another cyclic ester of selenic acid, C2H2O8Se2.C4H8O2, crystalizes from the reaction mixture after a few days. The reaction of selenium trioxide with 1,4-dioxane in sulfur dioxide was attempted with the aim of isolating the adduct. An equimolar amount of 1,4-dioxane was very slowly added under vigorous stirring to a saturated solution of selenium trioxide in sulfur dioxide at -15 cent. deg. After evaporation of all sulfur dioxide, a white microcrystalline solid was isolated. The content of Se(VI) established by elemental analysis matches the content of selenium in C4H8O2.SeO3. The Raman spectrum of this product corresponds to the spectra of other known selenium trioxide adducts with organic oxygen donors.

Links

MSM 143100011, plan (intention)

Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles

Citovat

RICHTERA, Lukáš and Jiří TOUŽÍN. The Reaction of Selenium Trioxide with 1,4-Dioxane. In Sborník příspěvků IV. seminář Pokroky v anorganické chemii. Brno: Masarykova univerzita v Brně, 2002, p. 56-57. ISBN 80-210-2951-X.

@inproceedings{483585,
   author = {Richtera, Lukáš and Toužín, Jiří},
   address = {Brno},
   booktitle = {Sborník příspěvků IV. seminář Pokroky v anorganické chemii},
   keywords = {DA-complex; Selenium trioxide; 1;4-Dioxane; Crystal structure; Raman spectra},
   language = {eng},
   location = {Brno},
   isbn = {80-210-2951-X},
   pages = {56-57},
   publisher = {Masarykova univerzita v Brně},
   title = {The Reaction of Selenium Trioxide with 1,4-Dioxane},
   year = {2002}
}

TY  - JOUR
ID  - 483585
AU  - Richtera, Lukáš - Toužín, Jiří
PY  - 2002
TI  - The Reaction of Selenium Trioxide with 1,4-Dioxane
PB  - Masarykova univerzita v Brně
CY  - Brno
SN  - 802102951X
KW  - DA-complex
KW  - Selenium trioxide
KW  - 1;4-Dioxane
KW  - Crystal structure
KW  - Raman spectra
N2  - In effort to investigate molecular structures and spectral properties of the selenium trioxide adducts with organic oxygen donor we decided to verify the preparation of the selenium trioxide adducts with 1,4-dioxane. In this reaction was not possible to eliminate reduction of Se(VI) to Se completely due to high melting point of 1,4-dioxane. A white precipitate containing Se(VI) was formed as selenium trioxide dissolved. The Raman spectrum of this product differs substantially from spectra of other donor-acceptor compounds. A glass-like solid was isolated after the solvent removal under vacuum from the filtrate. Sublimation of this glass-like material at 50 cent. deg. under vacuum gave a small amount of cyclic ester C2H4O4Se. Another cyclic ester of selenic acid, C2H2O8Se2.C4H8O2, crystalizes from the reaction mixture after a few days. The reaction of selenium trioxide with 1,4-dioxane in sulfur dioxide was attempted with the aim of isolating the adduct. An equimolar amount of 1,4-dioxane was very slowly added under vigorous stirring to a saturated solution of selenium trioxide in sulfur dioxide at -15 cent. deg. After evaporation of all sulfur dioxide, a white microcrystalline solid was isolated. The content of Se(VI) established by elemental analysis matches the content of selenium in C4H8O2.SeO3. The Raman spectrum of this product corresponds to the spectra of other known selenium trioxide adducts with organic oxygen donors.
ER  -

RICHTERA, Lukáš and Jiří TOUŽÍN. The Reaction of Selenium Trioxide with 1,4-Dioxane. In \textit{Sborník příspěvků IV. seminář Pokroky v anorganické chemii}. Brno: Masarykova univerzita v Brně, 2002, p.~56-57. ISBN~80-210-2951-X.

Detailed Information on Publication Record