The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x
5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2

J 2003

The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2

KOPEL, P., Z. TRÁVNÍČEK, Jaromír MAREK, M. KORABIK, J. MROZINSKI et. al.

Basic information

Original name

The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2

Authors

KOPEL, P. (203 Czech Republic), Z. TRÁVNÍČEK (203 Czech Republic), Jaromír MAREK (203 Czech Republic, guarantor), M. KORABIK (616 Poland) and J. MROZINSKI (616 Poland)

Edition

Polyhedron, Velká Británie, PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 2003, 0277-5387

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 1.584

RIV identification code

RIV/00216224:14310/03:00007940

Organization unit

Faculty of Science

Keywords in English

structure; copper(II); thiodiglycolic acid

Abstract

V originále

Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2-) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 . 5H2O (1) and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where PHEN=1,10-phenanthroline, H2tdga=thiodiglycolic acid, PMDIEN=N,N,N',N',N''-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9-300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner.

Links

GA203/99/0067, research and development project

Name: Pronájem krystalografických databází

Citovat

KOPEL, P., Z. TRÁVNÍČEK, Jaromír MAREK, M. KORABIK and J. MROZINSKI. The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2. Polyhedron. Velká Británie: PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 2003, vol. 22, No 3, p. 411-418. ISSN 0277-5387.

@article{483803,
   author = {Kopel, P. and Trávníček, Z. and Marek, Jaromír and Korabik, M. and Mrozinski, J.},
   article_location = {Velká Británie},
   article_number = {3},
   keywords = {structure; copper(II); thiodiglycolic acid},
   language = {eng},
   issn = {0277-5387},
   journal = {Polyhedron},
   title = {The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2},
   volume = {22},
   year = {2003}
}

TY  - JOUR
ID  - 483803
AU  - Kopel, P. - Trávníček, Z. - Marek, Jaromír - Korabik, M. - Mrozinski, J.
PY  - 2003
TI  - The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2
JF  - Polyhedron
VL  - 22
IS  - 3
SP  - 411
EP  - 411
PB  - PERGAMON-ELSEVIER SCIENCE LTD, OXFORD
SN  - 02775387
KW  - structure
KW  - copper(II)
KW  - thiodiglycolic acid
N2  - Mixed-ligand binuclear Cu(II) complexes involving thiodiglycolate(2-) anion and nitrogen-donor ligands in the coordination sphere of composition [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 . 5H2O (1) and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2 (2), where PHEN=1,10-phenanthroline, H2tdga=thiodiglycolic acid, PMDIEN=N,N,N',N',N''-pentamethyldiethylenetriamine, have been prepared. Temperature dependence of magnetic susceptibility, EPR spectroscopy and single crystal X-ray analysis has been used to characterize these compounds. Magnetic susceptibility measurements over the 1.9-300 K temperature range revealed a weak antiferromagnetic interaction between two copper atoms with the exchange integral value 2J=-4.80 cm-1 for 1 and -0.71 cm-1 for 2. The bridging dianion of thiodiglycolic acid is coordinated in each of the two complexes in a different manner.
ER  -

KOPEL, P., Z. TRÁVNÍČEK, Jaromír MAREK, M. KORABIK and J. MROZINSKI. The crystal structures of [(phen)2Cu(mu-tdga)Cu(phen)](NO3)2 x 5H2O and [(H2O)(pmdien)Cu(mu-tdga)Cu(pmdien)(H2O)](ClO4)2. \textit{Polyhedron}. Velká Británie: PERGAMON-ELSEVIER SCIENCE LTD, OXFORD, 2003, vol.~22, No~3, p.~411-418. ISSN~0277-5387.

Detailed Information on Publication Record