MADEROVÁ, J., Jaromír MAREK and F. PAVELČÍK. [N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, vol. 59, No 5, p. m178-m180, 3 pp. ISSN 0108-2701.
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Basic information
Original name [N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate
Authors MADEROVÁ, J. (703 Slovakia), Jaromír MAREK (203 Czech Republic, guarantor) and F. PAVELČÍK (703 Slovakia).
Edition Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.828
RIV identification code RIV/00216224:14310/03:00008554
Organization unit Faculty of Science
UT WoS 000182656300011
Keywords in English structure; cobalt(III)
Tags cobalt(III), structure
Changed by Changed by: JUDr. Jarmila Friedmannová, učo 401. Changed: 31/5/2004 15:39.
Abstract
The mononuclear title complex, [Co(C6H6NO6)(C2H8N2)].3H2O, contains an octahedrally coordinated Co(III) atom. The N-(carboxymethyl)aspartate moiety is coordinated as a tetradentate ligand, providing an OONO-donor set and forming two trans five-membered chelate rings and one six-membered chelate ring. A seven-membered chelate ring is also formed, which consists of part of the six-membered chelate ring and part of one of the five-membered chelate rings. The crystal structure of the complex is stabilized by hydrogen bonds with three water molecules.
Links
GA203/02/0436, research and development projectName: Aplikace krystalografických databází ve vědecké praxi
MSM 143100005, plan (intention)Name: Strukturně-funkční vztahy biomolekul a jejich role v metabolismu
Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular Structure-function Relationships and their role in the Metabolism
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