J 2003

[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate

MADEROVÁ, J., Jaromír MAREK and F. PAVELČÍK

Basic information

Original name

[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate

Authors

MADEROVÁ, J. (703 Slovakia), Jaromír MAREK (203 Czech Republic, guarantor) and F. PAVELČÍK (703 Slovakia)

Edition

Acta Crystallographica Section C: Crystal Structure, Chester, UK, International Union of Crystallography, 2003, 0108-2701

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.828

RIV identification code

RIV/00216224:14310/03:00008554

Organization unit

Faculty of Science

UT WoS

000182656300011

Keywords in English

structure; cobalt(III)

Tags

Změněno: 31/5/2004 15:39, JUDr. Jarmila Friedmannová

Abstract

V originále

The mononuclear title complex, [Co(C6H6NO6)(C2H8N2)].3H2O, contains an octahedrally coordinated Co(III) atom. The N-(carboxymethyl)aspartate moiety is coordinated as a tetradentate ligand, providing an OONO-donor set and forming two trans five-membered chelate rings and one six-membered chelate ring. A seven-membered chelate ring is also formed, which consists of part of the six-membered chelate ring and part of one of the five-membered chelate rings. The crystal structure of the complex is stabilized by hydrogen bonds with three water molecules.

Links

GA203/02/0436, research and development project
Name: Aplikace krystalografických databází ve vědecké praxi
MSM 143100005, plan (intention)
Name: Strukturně-funkční vztahy biomolekul a jejich role v metabolismu
Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular Structure-function Relationships and their role in the Metabolism