| MAREK, Jaromír, P. KOPEL and Z. TRÁVNÍČEK. Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide. Acta Crystallographica Section C: Crystal Structure. Chester, UK: International Union of Crystallography, 2003, vol. 59, No 10, p. m399-m401, 3 pp. ISSN 0108-2701. |
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@article{488531,
author = {Marek, Jaromír and Kopel, P. and Trávníček, Z.},
article_location = {Chester, UK},
article_number = {10},
keywords = {Hydrogen bonding; Trithiocyanuric acid},
language = {eng},
issn = {0108-2701},
journal = {Acta Crystallographica Section C: Crystal Structure},
title = {Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide},
volume = {59},
year = {2003}
}
TY - JOUR
ID - 488531
AU - Marek, Jaromír - Kopel, P. - Trávníček, Z.
PY - 2003
TI - Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide
JF - Acta Crystallographica Section C: Crystal Structure
VL - 59
IS - 10
SP - m399-m401
EP - m399-m401
PB - International Union of Crystallography
SN - 01082701
KW - Hydrogen bonding
KW - Trithiocyanuric acid
N2 - The title compound, [Na(C12H8N2)3](C3H2N3S3), contains an Na+ centre which is ionicly bonded to three 1,10-phenanthroline (phen) ligands and one trithiocyanurate(1-) (ttcH2) anion. In the crystal structure, the anions are linked via hydrogen bonds to form linear chains. The S and H atoms of the ttcH2 anion participate in intermolecular N-HS hydrogen bonding, with NS distances of 3.298 (2) and 3.336 (2) A. The phen ligands are almost parallel, with dihedral angles of 3.92 (5), 11.75 (5) and 15.45 (5) deg; moreover, they are nearly perpendicular to the ttcH2 chains, with angles of 81.94 (7), 85.86 (7) and 85.96 (7)deg.
ER -
MAREK, Jaromír, P. KOPEL and Z. TRÁVNÍČEK. Tris(1,10-phenanthroline)sodium 2,4,6-trimercapto-1,3,5-triazin-1-ide. \textit{Acta Crystallographica Section C: Crystal Structure}. Chester, UK: International Union of Crystallography, 2003, vol.~59, No~10, p.~m399-m401, 3 pp. ISSN~0108-2701.
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