CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE
DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and
alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l
PTC and/or by Ultrasound

D 2003

CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound

PAZDERA, Pavel and Jan ŠIMBERA

Basic information

Original name

CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound

Authors

PAZDERA, Pavel (203 Czech Republic, guarantor) and Jan ŠIMBERA (203 Czech Republic)

Edition

1. vyd. Basel, Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition, p. 22-6, 5 pp. 2003

Publisher

Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10401 Organic chemistry

Country of publisher

Switzerland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

URL

RIV identification code

RIV/00216224:14310/03:00009383

Organization unit

Faculty of Science

ISBN

3-906980-13-8

Keywords in English

"Green Chemistry"; SUSTAINABLE DEVELOPMENT; Nitrourea; sonochemical solid-liquid PTC; cyclic ketones

Abstract

V originále

Facile methods for direct ethoxycarbonylation and carbamoylation reactions on some cyclic ketones is described and discussed. A principle of this solution is an application of ultrasonic solid-liquid phase-transfer-catalysis for an enolate anion generation. Enolate anion reacts further with electrophilic reagents, i. e. with ethyl chlorocarbonate in the case of ethoxycarbonylation or nitrourea for carbamoylation reaction.

Links

MSM 143100011, plan (intention)

Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles

Citovat

PAZDERA, Pavel and Jan ŠIMBERA. CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound. In Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition. 1st ed. Basel: Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland, 2003, p. 22-6, 5 pp. ISBN 3-906980-13-8.

@inproceedings{491743,
   author = {Pazdera, Pavel and Šimbera, Jan},
   address = {Basel},
   booktitle = {Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition},
   edition = {1.},
   keywords = {"Green Chemistry"; SUSTAINABLE DEVELOPMENT; Nitrourea; sonochemical solid-liquid PTC; cyclic ketones},
   language = {eng},
   location = {Basel},
   isbn = {3-906980-13-8},
   pages = {22-6},
   publisher = {Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland},
   title = {CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound},
   url = {http://www.mdpi.org/ecsoc-7.htm},
   year = {2003}
}

TY  - JOUR
ID  - 491743
AU  - Pazdera, Pavel - Šimbera, Jan
PY  - 2003
TI  - CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound
PB  - Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland
CY  - Basel
SN  - 3906980138
KW  - "Green Chemistry"
KW  - SUSTAINABLE DEVELOPMENT
KW  - Nitrourea
KW  - sonochemical solid-liquid PTC
KW  - cyclic ketones
UR  - http://www.mdpi.org/ecsoc-7.htm
N2  - Facile methods for direct ethoxycarbonylation and carbamoylation reactions on some cyclic ketones is described and discussed. A principle of this solution is an application of ultrasonic solid-liquid phase-transfer-catalysis for an enolate anion generation. Enolate anion reacts further with electrophilic reagents, i. e. with ethyl chlorocarbonate in the case of ethoxycarbonylation or nitrourea for carbamoylation reaction.
ER  -

PAZDERA, Pavel and Jan ŠIMBERA. CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound. In \textit{Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition}. 1st ed. Basel: Publisher MDPI, Matthaeusstrasse 11, CH-4057 Basel, Switzerland, 2003, p.~22-6, 5 pp. ISBN~3-906980-13-8.

Detailed Information on Publication Record