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@article{493079,
author = {Taraba, Jan and Žák, Zdirad},
article_number = {42},
keywords = {ionic form of PPh2Cl3; trichloride ion; single-crystal X-ray analysis; 31P; 1H; and 35Cl-NMR; Raman spectra},
language = {eng},
issn = {0020-1669},
journal = {INORGANIC CHEMISTRY},
title = {Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-},
volume = {2003},
year = {2003}
}
TY - JOUR
ID - 493079
AU - Taraba, Jan - Žák, Zdirad
PY - 2003
TI - Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-
JF - INORGANIC CHEMISTRY
VL - 2003
IS - 42
SP - 3591-4
EP - 3591-4
SN - 00201669
KW - ionic form of PPh2Cl3
KW - trichloride ion
KW - single-crystal X-ray analysis
KW - 31P
KW - 1H
KW - and 35Cl-NMR
KW - Raman spectra
N2 - An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh2Cl3 with excess chlorine. The identity of this species was established by single-crystal X-ray analysis, 31P, 1H, and 35Cl-NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by 31P-NMR spectra and single-crystal X-ray analysis.
ER -
TARABA, Jan and Zdirad ŽÁK. Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-. \textit{INORGANIC CHEMISTRY}. vol.~2003, No~42, p.~3591-4, 4 pp. ISSN~0020-1669. 2003.
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