Detailed Information on Publication Record
2003
Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-
TARABA, Jan and Zdirad ŽÁKBasic information
Original name
Diphenyldichlorophosphonium Trichloride - Chlorine Solvate 1:1, [PPh2Cl2]+Cl3-. Cl2, an Ionic Form of Diphenyltrichlorophosphorane. Crystal Structures of [PPh2Cl2]+Cl3-. Cl2 and [(PPh2Cl2)2]2+[InCl5]2-
Authors
TARABA, Jan (203 Czech Republic) and Zdirad ŽÁK (203 Czech Republic, guarantor)
Edition
INORGANIC CHEMISTRY, 2003, 0020-1669
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Czech Republic
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 3.389
RIV identification code
RIV/00216224:14310/03:00009532
Organization unit
Faculty of Science
Keywords in English
ionic form of PPh2Cl3; trichloride ion; single-crystal X-ray analysis; 31P; 1H; and 35Cl-NMR; Raman spectra
Tags
Změněno: 20/5/2004 10:13, RNDr. Jan Taraba, Ph.D.
Abstract
V originále
An ionic form of diphenyltrichlorophosphorane, namely, diphenyldichlorophosphonium trichloride isolated as a dichlorine solvate (1), was obtained by treating PPh2Cl3 with excess chlorine. The identity of this species was established by single-crystal X-ray analysis, 31P, 1H, and 35Cl-NMR and Raman spectra. Bis(diphenyldichlorophosphonium) pentachloroindate (2) was obtained by the reaction of diphenyltrichlorophosphorane with indium trichloride in dichloromethane for comparison purposes. Its identity was determined by 31P-NMR spectra and single-crystal X-ray analysis.
Links
| MSM 143100011, plan (intention) |
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