| JANCIK, Vojtech, Leslie W. PINEDA, Jiri PINKAS, Herbert W. ROESKY, Dante NECULAI, Ana M. NECULAI and Regine HERBST-IRMER. Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor. Angewandte Chemie International Edition. Weinheim: Wiley-VCH Verlag GmbH & Co., 2004, vol. 43, No 16, p. 2142 - 2145. ISSN 1433-7851. |
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@article{554202,
author = {Jancik, Vojtech and Pineda, Leslie W. and Pinkas, Jiri and Roesky, Herbert W. and Neculai, Dante and Neculai, Ana M. and HerbstandIrmer, Regine},
article_location = {Weinheim},
article_number = {16},
keywords = {aluminum amides carbenes hydroxides},
language = {eng},
issn = {1433-7851},
journal = {Angewandte Chemie International Edition},
title = {Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor},
volume = {43},
year = {2004}
}
TY - JOUR
ID - 554202
AU - Jancik, Vojtech - Pineda, Leslie W. - Pinkas, Jiri - Roesky, Herbert W. - Neculai, Dante - Neculai, Ana M. - Herbst-Irmer, Regine
PY - 2004
TI - Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor
JF - Angewandte Chemie International Edition
VL - 43
IS - 16
SP - 2142 - 2145
EP - 2142 - 2145
PB - Wiley-VCH Verlag GmbH & Co.
SN - 14337851
KW - aluminum amides carbenes hydroxides
N2 - We have presented a novel method for preparing aluminum amides and hydroxides from the corresponding chlorides. The main byproduct - N,N-di-tbutylimidazolium chloride - can be easily separated from the product by filtration and recycled to the free base. LAl(NH2)2 is to the best of our knowledge the first monomeric main-group metal diamide containing two terminal NH2 groups.
ER -
JANCIK, Vojtech, Leslie W. PINEDA, Jiri PINKAS, Herbert W. ROESKY, Dante NECULAI, Ana M. NECULAI and Regine HERBST-IRMER. Preparation of Monomeric LAl(NH2)2 The First Main-Group Metal Diamide Containing Two Terminal NH2 Groups in the Presence of a N-heterocyclic Carbene as HCl Acceptor. \textit{Angewandte Chemie International Edition}. Weinheim: Wiley-VCH Verlag GmbH \&{} Co., 2004, vol.~43, No~16, p.~2142 - 2145. ISSN~1433-7851.
|
