2004
Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)
TRÁVNÍČEK, Z.; V. MACHALA; L. SZUČOVÁ; M. MALOŇ; Jaromír MAREK et. al.Basic information
Original name
Square-Planar Nickel(II) O,O'-Dialkyldithiophosphato Complexes with Triphenylphosphine of the Type [NiX(S2P{OR}2)(PPh3)] (X = Cl, Br, I and NCS)
Authors
TRÁVNÍČEK, Z.; V. MACHALA; L. SZUČOVÁ; M. MALOŇ and Jaromír MAREK ORCID
Edition
Transition Metal Chemistry, Netherlands, Kluwer Academic Publishers, 2004, 0340-4285
Other information
Language
English
Type of outcome
Article in a journal
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
Netherlands
Confidentiality degree
is not subject to a state or trade secret
Impact factor
Impact factor: 0.857
Organization unit
Faculty of Science
UT WoS
000221360700002
Keywords in English
Dialkyl Dithiophosphates; Crystal-structure; Adducts; Ligands
Changed: 4/6/2004 13:43, doc. RNDr. Jaromír Marek, Ph.D.
Abstract
In the original language
A series of new [NiX(S2P{O-c-Hex}2)(PPh3)] (X = Cl-, Br-, I- and NCS-) (1)-(4) and [Ni(NCS) (S2P{OR}2)(PPh3)] [R = n-Pr (5), i-Pr (6)] complexes has been synthesized and characterized by elemental analyses, f.i.r., i.r., u.v.-vis., 1H-, 13C{1H}- and 31P{1H}-n.m.r. spectra, magnetochemical and conductivity measurements. A single crystal X-ray analysis of [Ni(NCS)(S2P{O-n-Pr}2)(PPh3)] (5) reveals the molecular structure of the complex and confirms a square-planar geometry around the central atom of nickel with the NCS anion coordinated via the nitrogen atom.
Links
| GA203/02/0436, research and development project |
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