SOPOUŠEK, Jiří and Rudolf FORET. Weld Joints Simulations of Heat-resistant Steels. In CALPHAD XXXIII. Krakow: Institute of Metallurgy and Material Science, Krakow, Polish Academy of Sciences, 2004, p. 148.
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Basic information
Original name Weld Joints Simulations of Heat-resistant Steels
Name in Czech Simulace svarových spojů žáropevných ocelí
Authors SOPOUŠEK, Jiří (203 Czech Republic) and Rudolf FORET (203 Czech Republic, guarantor).
Edition Krakow, CALPHAD XXXIII, p. 148-148, 2004.
Publisher Institute of Metallurgy and Material Science, Krakow, Polish Academy of Sciences
Other information
Original language English
Type of outcome Proceedings paper
Field of Study 10403 Physical chemistry
Country of publisher Poland
Confidentiality degree is not subject to a state or trade secret
RIV identification code RIV/00216224:14310/04:00011448
Organization unit Faculty of Science
Keywords in English diffusion; couple; DICTRA; ThermoCalc; Equilibrium; Activity
Tags activity, couple, DICTRA, Diffusion, equilibrium, ThermoCalc
Changed by Changed by: prof. RNDr. Jiří Sopoušek, CSc., učo 2405. Changed: 7/6/2004 11:31.
Abstract
Knowledge of microstructure stabilities is essential for reliable estimations of the lifetime limitations of materials and welded joints at higher temperatures. This information may be deduced from material phase diagrams and from heterogeneous weld joint simulations. The phase diagrams can be calculated using CALPHAD method [1]. This method complemented with appropriate diffusion approach [2], [3] can help us to simulate phase and element profile evolutions inside diffusion-affected zone of weld joint too. The heat-resistant steels (alloying base: Cr, Ni, Mo, V, C, N) and their weld joints are objects of our study. Thermodynamic database STEEL [4] and kinetic database DIF mentioned in [5] are used. The particullar results of the equilibrium calculations are presented as the phase diagram cross-sections of the selected heat-resistance steels. The same equilibrium calculations offer element activities too. The carbon activity temperature dependences were calculated for individual steels. The observed difference between the carbon activities of two different steels (at given temperature) enabled us to predict diffusion flow direction, which can be opposite then deduced from the carbon content in some steel combinations (carbon up-hill diffusion). The simulations respect the coexistence of different carbide phases in the materials and they are conducted on the assumption that under the examined conditions the local phase equilibrium holds and that diffusion is the control process of phase transformation. The phase diagram calculations and diffusion couple simulations involving time-distance dependences for phase and element redistributions in diffusion-affected zones enabled us to obtain a basic information, which allow to estimate thermodynamic and diffusion stabilities of the studied heat-resistant steels and their weld joints.
Abstract (in Czech)
Pro oceli na bázi Cr, Ni, Mo, V, C, V jsou predikovány fázové diagramy metodou CALPHAD. Pro sledované oceli jsou vypočteny aktivitní teplotní závislosti uhlíku. Je sledován i případ difúze proti koncentračnímu spádu. Součástí práce je simulace difúzních profilů sledovaných kombinací svarových spojů.
Links
GA106/03/0636, research and development projectName: Teoretické modelování a experimentální studium strukturní stability moderních žárupevných ocelí a jejich svarů
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