D 2004

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

BARTOŠ, Petr and Ctibor MAZAL

Basic information

Original name

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Name in Czech

Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

Authors

BARTOŠ, Petr (203 Czech Republic) and Ctibor MAZAL (203 Czech Republic, guarantor)

Edition

Praha, Chemické listy, IV. Mezioborové setkání mladých biologů, p. 274-274, 2004

Publisher

Česká společnost chemická

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10401 Organic chemistry

Country of publisher

Czech Republic

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 0.348

RIV identification code

RIV/00216224:14310/04:00010131

Organization unit

Faculty of Science

ISSN

Keywords in English

bicyclopentanes; staffanes; cyclodextrin; pseudorotaxanes; NMR
Změněno: 21/5/2009 17:31, doc. RNDr. Ctibor Mazal, CSc.

Abstract

V originále

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of [1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemistry of BCPs.

In Czech

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of [1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemistry of BCPs.

Links

ME 571, research and development project
Name: Substituované bicyklo [1.1.1.] pentany a [n] staffany
Investor: Ministry of Education, Youth and Sports of the CR, Substituted bicyclo /1.1.1./ pentans and únú staffants, Research and Development Programme KONTAKT (ME)
MSM 143100011, plan (intention)
Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů
Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles