Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water

BARTOŠ, Petr and Ctibor MAZAL. Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water. In Chemické listy, IV. Mezioborové setkání mladých biologů,. Praha: Česká společnost chemická, 2004, p. 274. ISSN 0009-2770.

Basic information

• Original name: Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water
• Name in Czech: Synthesis of 3,3'-substituted[2]staffane derivatives and NMR study of their inclusion complexes with beta-cyclodextrin in water
• Authors: BARTOŠ, Petr (203 Czech Republic) and Ctibor MAZAL (203 Czech Republic, guarantor).
• Edition: Praha, Chemické listy, IV. Mezioborové setkání mladých biologů, p. 274-274, 2004.
• Publisher: Česká společnost chemická

Other information

• Original language: English
• Type of outcome: Proceedings paper
• Field of Study: 10401 Organic chemistry
• Country of publisher: Czech Republic
• Confidentiality degree: is not subject to a state or trade secret
• Impact factor: Impact factor: 0.348
• RIV identification code: RIV/00216224:14310/04:00010131
• Organization unit: Faculty of Science
• ISSN: 0009-2770
• Keywords in English: bicyclopentanes; staffanes; cyclodextrin; pseudorotaxanes; NMR
• Tags: bicyclopentanes, cyclodextrin, NMR, pseudorotaxanes, staffanes

Abstract

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of [1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemistry of BCPs.

Abstract (in Czech)

Derivatives of bicyclo[1.1.1]pentante (BCP) I were recognized as very interesting class of compounds due to their structural features. For example, BCP cage represents a basic construction module for rigid rod like molecules . [n]staffanes II, the fundamental part of suggested molecular size construction set1. Having the set of predefined properties with appropriate tools of supramolecular chemistry in hand, one might be able to construct novel molecular materials. Since practically useful synthesis of [1.1.1]propellane had been found, synthetic aspects of BCP chemistry became relatively developed recently2. On the other hand, there is little known about supramolecular chemistry of BCP derivatives so far. Inspired with Berg et al. (cf.3) describing complexation of bicyclo[2.2.2]octane derivatives with cyclodextrins (CD) and with CD-based pseudo-rotaxane model4 in our minds, we focused our interest to the host-guest chemistry of BCPs.

Links

• ME 571, research and development project: Name: Substituované bicyklo [1.1.1.] pentany a [n] staffany

Investor: Ministry of Education, Youth and Sports of the CR, Substituted bicyclo /1.1.1./ pentans and únú staffants, Research and Development Programme KONTAKT (ME)

• MSM 143100011, plan (intention): Name: Struktura a vazebné poměry, vlastnosti a analýza syntetických a přírodních molekulových ansamblů

Investor: Ministry of Education, Youth and Sports of the CR, Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles