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@article{556373,
author = {Zak, Zdirad and Taraba, Jan},
article_location = {The United States of America},
article_number = {4-5},
keywords = {Polyheterocycle; preparation; X-ray structure; NMR},
language = {eng},
issn = {1042-6507},
journal = {Phosphorus, Sulfur, and Silicon and the related elements},
title = {New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group},
volume = {179/2004},
year = {2004}
}
TY - JOUR
ID - 556373
AU - Zak, Zdirad - Taraba, Jan
PY - 2004
TI - New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group
JF - Phosphorus, Sulfur, and Silicon and the related elements
VL - 179/2004
IS - 4-5
SP - 839-843
EP - 839-843
PB - Taylor and Francis Inc.
SN - 10426507
KW - Polyheterocycle
KW - preparation
KW - X-ray structure
KW - NMR
N2 - During our studies of the reactions of -N(H)SiMe3 and -N(Me)SiMe3 derivatives of Cl3PNSO2Cl with acetonitrile and BCl3 we have obtained six-membered polyheteroatomic cycles -P(Cl2)NSO2(Cl)N(H)C(Me)Nand -P(Cl2)NS(O)(Cl)OB(Cl2)N(Me) [1,2]. In the system Ph2PCl3, H2NSO2Cl and HN(SiMe3)2 we have identified and isolated several P-N-S cycles, e.g. the reaction of Ph2PCl3 with H2NSO2Cl gives Ph2ClPNSO2Cl [3] which with HN(SiMe3)2 reacts to ĄS(O2)N(H)P(Ph)2N(H)SO2N(H)P(Ph)2N(H), ĄS(O2)N(H)S(O2)N(H)P(Ph)2N(H)P(Ph)2N(H)and Ą[S(O2)N(H)P(Ph)2NP(Ph)2N(H)]+Cl-; Ph2PCl3 with HN(SiMe3)2 gives N[P(Ph)2N(H)SiMe3]2+ Cl-, and H2NSO2Cl with HN(SiMe3)2 leads to SO2(NHSiMe3)2. The reaction of Ph2PCl3 with HN(SiMe3)2 gives N(P(Ph)2NHSiMe3)2Cl in a very good yield which was further used to syntheses of metal-containing heterocycles. By the reaction of N[P(Ph)2N(H)SiMe3]2+Cl- with some covalent halogenides we have obtained six-membered heterocycles containing B, As, In, and Sn. The same cyclic compounds can also obtained by the reaction of N[P(Ph2)NH2]2+Cl- or HN(P(R2)N(H)SiMe3)2 with covalent halogenides [4,5,6]. However, the synthetic route via N[P(Ph)2NHSiMe3]2+Cl- is more convenient and gives the compounds in almost quantitative yields. The identity of all compounds was unambiguously established by their X-ray structure determination.
ER -
ZAK, Zdirad and Jan TARABA. New Polyheteroatomic Cyclic Molecules Containing Elements of the 13. - 16. Group. \textit{Phosphorus, Sulfur, and Silicon and the related elements}. The United States of America: Taylor and Francis Inc., 2004, 179/2004, 4-5, p.~839-843. ISSN~1042-6507.
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