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@inproceedings{566531,
author = {Mazal, Ctibor and Bartoš, Petr and Škarka, Ondřej and Michl, Josef},
address = {Praha},
booktitle = {Chemické listy, International Conference on Supramolecular Science & Technology, ICSS&T 2004 Congress Abstract Book},
keywords = {bicyclopentanes; staffanes},
language = {eng},
location = {Praha},
pages = {s59-s60},
publisher = {Česká společnost chemická},
title = {Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.},
year = {2004}
}
TY - JOUR
ID - 566531
AU - Mazal, Ctibor - Bartoš, Petr - Škarka, Ondřej - Michl, Josef
PY - 2004
TI - Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set.
PB - Česká společnost chemická
CY - Praha
KW - bicyclopentanes
KW - staffanes
N2 - We are introducing a new structural pattern 3 based on highly strained bicylo[1.1.1]pentane cage, which benefits from placing additional functionalities (FG) on its bridge positions. The new substituents are on two parallel bonds in positions 2 and 4, perpendicular to 1-3 axis of the cage. Such configuration enables interaction of the functionalities in an .equatorial. plane of the cage defined by its rotation around the 1-3 axis. If used in staffanes, these functionalities (polarizable, electron donating or accepting, ionizable, etc.) can propagate the interaction along the light of such molecular rod.
ER -
MAZAL, Ctibor, Petr BARTOŠ, Ondřej ŠKARKA a Josef MICHL. Substituted bicyclo[1.1.1]pentanes for molecular and supramolecular costruction set. In \textit{Chemické listy, International Conference on Supramolecular Science \&{} Technology, ICSS\&{}T 2004 Congress Abstract Book}. Praha: Česká společnost chemická. s.~s59-s60, 1 s. ISSN~0009-2770. 2004.
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