Application of elimination voltammetry in the study of electroplating processes on the graphite electrode

ORIŇÁKOVÁ, Renáta, Libuše TRNKOVÁ, Miriam GÁLOVÁ and Magdalena ŠUPICOVÁ. Application of elimination voltammetry in the study of electroplating processes on the graphite electrode. Electrochimica Acta. Ireland: Elsevier Science Ireland Ltd, 2004, vol. 49, No 1, p. 3587 - 3594. ISSN 0013-4686.

Basic information

Original name

Application of elimination voltammetry in the study of electroplating processes on the graphite electrode

Name in Czech

Aplikace eliminační voltametrie při studiu elektrodových procesů pokovování na grafitové elektrodě

Authors

ORIŇÁKOVÁ, Renáta (703 Slovakia), Libuše TRNKOVÁ (203 Czech Republic, guarantor), Miriam GÁLOVÁ (703 Slovakia) and Magdalena ŠUPICOVÁ (703 Slovakia)

Edition

Electrochimica Acta, Ireland, Elsevier Science Ireland Ltd, 2004, 0013-4686

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Other information

Language

English

Type of outcome

Article in a journal

Field of Study

10405 Electrochemistry

Country of publisher

Czech Republic

Confidentiality degree

is not subject to a state or trade secret

Impact factor

Impact factor: 2.341

RIV identification code

RIV/00216224:14310/04:00011225

Organization unit

Faculty of Science

UT WoS

000222253700015

Keywords in English

Elimination voltammetry; Electrodeposition; Graphite electrode; Cyclic voltammetry; Nickel

Tags

cyclic voltammetry, Electrodeposition, Elimination voltammetry, Graphite electrode, nickel

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Abstract

V originále

The electrode reaction mechanism of electrolytical coating by nickel on paraffin impregnated graphite electrode (PIGE) was investigated by cyclic voltammetry (CV) and elimination voltammetry with linear scan (EVLS). The EVLS, a relatively new method of processing electrochemical signals obtained by voltammetry, is able to eliminate some individual chosen currents from total voltammetric currents measured at different scan rates. During the electrodeposition of metals on the graphite electrode, hydrogen evolved from aqueous acidic solutions interferes with the plating process. The elimination of kinetic current arising due to hydrogen evolution enables one to study other processes proceeding at the electrode. Cyclic voltammograms for metal coating deposition/dissolution on the graphite electrode were measured at three scan rates (12.5, 25 and 50 mV/s) and the EVLS functions were calculated for one or two eliminated currents. The results indicate the occurrence of surface reactions with the adsorption of intermediates on graphite. The application of EVLS provides deeper insight into the mechanism of electrode reaction during metal deposition.

In Czech

Aplikace eliminační voltametrie při studiu elektrodových procesů pokovování na grafitové elektrodě

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Links

GA203/02/0422, research and development project	Name: Nové směry v elektrochemii nukleových kyselin a jejich aplikace v chemii životního prostředí Investor: Czech Science Foundation, New trends in electrochemistry of nucleic acids and their applications in enviromental chemistry
IAA1163201, research and development project	Name: Využití adsorptivní přenosové a eliminační techniky pro elektrochemickou analýzu oligonukleotidů a nukleových kyselin Investor: Academy of Sciences of the Czech Republic, Application of adsorptive transfer and elemination techniques in oligonucleotides and nucleic acids analysis.