Detailed Information on Publication Record
2005
From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide
SPÍCHAL, Zdeněk, Marek NEČAS and Jiří PINKASBasic information
Original name
From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide
Name in Czech
Od parket k cihlové zdi: řada lanthanoidových koordinačních polymerů s bis(difenylfosfino)ethan dioxidem
Authors
SPÍCHAL, Zdeněk (203 Czech Republic), Marek NEČAS (203 Czech Republic, guarantor) and Jiří PINKAS (203 Czech Republic)
Edition
INORGANIC CHEMISTRY, Spojené státy americké, American Chemical Society, Washington DC, 2005, 0020-1669
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10402 Inorganic and nuclear chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 3.851
RIV identification code
RIV/00216224:14310/05:00013646
Organization unit
Faculty of Science
UT WoS
000227764700046
Keywords in English
Lanthanides Coordination Polymers
Změněno: 25/6/2009 11:44, doc. Mgr. Marek Nečas, Ph.D.
V originále
A series of new layered coordination polymers consisting of Ln[Ph2P(O)-CH2CH2-P(O)Ph2]1.5 monomeric units, where Ln ) Pr(NO3)3, Nd(NO3)3, NdCl3, Sm(NO3)3, GdCl3, Dy(NO3)3, were synthesized and structurally characterized. The majority of prepared compounds display approximately rectangular building blocks. However, the adopted architecture strongly depends on additional nonbridging ligands in the coordination sphere of the cation, as well as on the reaction conditions and the employed solvent. Accordingly, the solvothermally prepared polymers exhibit either parquet-floor or brick-wall architecture, whereas the polymers from gel-diffusion reactions resemble honeycomb networks. The solvothermal reaction of the smallest lanthanide cation Lu3+ with Ph2P(O)-CH2CH2-P(O)Ph2 led to a molecular compound instead of a polymer.
In Czech
Byla připravena a strukturně charakterizována řada nových vrstevnatých koordinačních polymerů Ln[Ph2P(O)-CH2CH2-P(O)Ph2]1.5 , pro Ln Pr(NO3)3, Nd(NO3)3, NdCl3, Sm(NO3)3, GdCl3, Dy(NO3)3.
Links
| MSM0021622410, plan (intention) |
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