MÜLLER, Pavel, Andre LOUPY and Petr KLÁN. The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water. Journal of Photochemistry and Photobiology A: Chemistry. Amsterdam, The Netherlands: Elsevier Science, 2005, vol. 172, No 2, p. 146-150. ISSN 1010-6030.
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Basic information
Original name The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water
Name in Czech Fotochemie valerofenonu a nitroanisolu v peháté vod
Authors MÜLLER, Pavel (203 Czech Republic), Andre LOUPY (250 France) and Petr KLÁN (203 Czech Republic, guarantor).
Edition Journal of Photochemistry and Photobiology A: Chemistry, Amsterdam, The Netherlands, Elsevier Science, 2005, 1010-6030.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10401 Organic chemistry
Country of publisher Netherlands
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 2.286
RIV identification code RIV/00216224:14310/05:00012595
Organization unit Faculty of Science
UT WoS 000229159900007
Keywords in English Photochemistry; Microwave; Electrodeless discharge lamp; High-temperature water; Valerophenone
Tags Electrodeless Discharge Lamp, High-temperature water, microwave, Photochemistry, Valerophenone
Tags International impact
Changed by Changed by: prof. RNDr. Petr Klán, Ph.D., učo 32829. Changed: 23/6/2009 15:28.
Abstract
Two temperature-sensitive model photochemical reactions, the Norrish Type II reaction and photochemical nucleophilic aromatic substitution on 4-nitroanisole by the hydroxide ion, carried out in high-temperature water (100-200 oC) in a pressurized vessel under microwave heating, are reported. The observed chemoselectivity and the ability to increase the solubility of hydrophobic organic compounds in this environmentally friendly solvent are promising results for prospective green (photo)chemical applications.
Abstract (in Czech)
Two temperature-sensitive model photochemical reactions, the Norrish Type II reaction and photochemical nucleophilic aromatic substitution on 4-nitroanisole by the hydroxide ion, carried out in high-temperature water (100-200 oC) in a pressurized vessel under microwave heating, are reported. The observed chemoselectivity and the ability to increase the solubility of hydrophobic organic compounds in this environmentally friendly solvent are promising results for prospective green (photo)chemical applications.
Links
GA203/02/0879, research and development projectName: Vliv mikrovlnného záření na fotochemické reakce
Investor: Czech Science Foundation, Microwave Irradiation Effect on Photochemical Reactions
MSM0021622413, plan (intention)Name: Proteiny v metabolismu a při interakci organismů s prostředím
Investor: Ministry of Education, Youth and Sports of the CR, Proteins in metabolism and interaction of organisms with the environment
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