J 2005

The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water

MÜLLER, Pavel, Andre LOUPY and Petr KLÁN

Basic information

Original name

The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water

Name in Czech

Fotochemie valerofenonu a nitroanisolu v peháté vod

Authors

MÜLLER, Pavel (203 Czech Republic), Andre LOUPY (250 France) and Petr KLÁN (203 Czech Republic, guarantor)

Edition

Journal of Photochemistry and Photobiology A: Chemistry, Amsterdam, The Netherlands, Elsevier Science, 2005, 1010-6030

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10401 Organic chemistry

Country of publisher

Netherlands

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.286

RIV identification code

RIV/00216224:14310/05:00012595

Organization unit

Faculty of Science

UT WoS

000229159900007

Keywords in English

Photochemistry; Microwave; Electrodeless discharge lamp; High-temperature water; Valerophenone

Tags

Tags

International impact
Změněno: 23/6/2009 15:28, prof. RNDr. Petr Klán, Ph.D.

Abstract

ORIG CZ

V originále

Two temperature-sensitive model photochemical reactions, the Norrish Type II reaction and photochemical nucleophilic aromatic substitution on 4-nitroanisole by the hydroxide ion, carried out in high-temperature water (100-200 oC) in a pressurized vessel under microwave heating, are reported. The observed chemoselectivity and the ability to increase the solubility of hydrophobic organic compounds in this environmentally friendly solvent are promising results for prospective green (photo)chemical applications.

In Czech

Two temperature-sensitive model photochemical reactions, the Norrish Type II reaction and photochemical nucleophilic aromatic substitution on 4-nitroanisole by the hydroxide ion, carried out in high-temperature water (100-200 oC) in a pressurized vessel under microwave heating, are reported. The observed chemoselectivity and the ability to increase the solubility of hydrophobic organic compounds in this environmentally friendly solvent are promising results for prospective green (photo)chemical applications.

Links

GA203/02/0879, research and development project
Name: Vliv mikrovlnného záření na fotochemické reakce
Investor: Czech Science Foundation, Microwave Irradiation Effect on Photochemical Reactions
MSM0021622413, plan (intention)
Name: Proteiny v metabolismu a při interakci organismů s prostředím
Investor: Ministry of Education, Youth and Sports of the CR, Proteins in metabolism and interaction of organisms with the environment