Detailed Information on Publication Record
2006
Pressurised solvent extraction of nitrated derivatives of polycyclic aromatic hydrocarbons from roadside dust
PRYČEK, Jiří, Miroslav CIGANEK and Zdeněk ŠIMEKBasic information
Original name
Pressurised solvent extraction of nitrated derivatives of polycyclic aromatic hydrocarbons from roadside dust
Name in Czech
Extrakce nitroderivátů polycyklických aromatických uhlovodíků z prachu vozovky pomocí zrychlené extrakce rozpouštědlem
Authors
PRYČEK, Jiří (203 Czech Republic), Miroslav CIGANEK (203 Czech Republic) and Zdeněk ŠIMEK (203 Czech Republic, guarantor)
Edition
International Journal of Environmental Analytical Chemistry, Taylor and Francis, 2006, 1029-0397
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10406 Analytical chemistry
Country of publisher
Czech Republic
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 0.917
RIV identification code
RIV/00216224:14310/06:00016706
Organization unit
Faculty of Science
UT WoS
000236700500002
Keywords in English
Nitro-PAH; Pressurised solvent extraction; Roadside dust; Silica gel; Clean-up
Tags
International impact, Reviewed
Změněno: 31/1/2008 15:56, doc. RNDr. Zdeněk Šimek, CSc.
V originále
An analytical method based upon the pressurised solvent extraction and gas chromatography and mass spectrometry (GC-MS) for analysis of nitrated derivatives of polycyclic aromatic hydrocarbons (nitro-PAHs) in roadside dust has been developed. Five nitro-PAHs (1-nitronaphthalene, 1-nitropyrene, 9-nitroanthracene, 2-nitrofluorene, 6-nitrochrysene) were chosen for this study because of their variable physical properties and effect on human health. Experiments with spiked inert matrix were used for the best extraction conditions finding. Different extraction conditions (temperature, pressure, solvents and duration of extraction cycle) were examined. The highest recoveries were observed at the extraction pressure of 14 MPa, temperature of 100C and two cycles of 5 min extraction time, when dichloromethane was used as an extraction solvent. These conditions were applied to the extraction of nitro- PAHs from roadside dust. After extraction the nitro-PAHs fraction was isolated by the silica gel column chromatography. The GC-MS detector was used for analyses of the extracts. Recoveries of nitro-PAHs after extraction from roadside dust ranged from 60% for 9-nitroanthracene to 108% for 6-nitrochrysene.
In Czech
An analytical method based upon the pressurised solvent extraction and gas chromatography and mass spectrometry (GC-MS) for analysis of nitrated derivatives of polycyclic aromatic hydrocarbons (nitro-PAHs) in roadside dust has been developed. Five nitro-PAHs (1-nitronaphthalene, 1-nitropyrene, 9-nitroanthracene, 2-nitrofluorene, 6-nitrochrysene) were chosen for this study because of their variable physical properties and effect on human health. Experiments with spiked inert matrix were used for the best extraction conditions finding. Different extraction conditions (temperature, pressure, solvents and duration of extraction cycle) were examined. The highest recoveries were observed at the extraction pressure of 14 MPa, temperature of 100C and two cycles of 5 min extraction time, when dichloromethane was used as an extraction solvent. These conditions were applied to the extraction of nitro- PAHs from roadside dust. After extraction the nitro-PAHs fraction was isolated by the silica gel column chromatography. The GC-MS detector was used for analyses of the extracts. Recoveries of nitro-PAHs after extraction from roadside dust ranged from 60% for 9-nitroanthracene to 108% for 6-nitrochrysene.
Links
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