Experimental and quantum-chemical studies of N-15 NMR
coordination shifts in palladium and platinum chloride
complexes with pyridine, 2,2 '-bipyridine and
1,10-phenanthroline

J 2006

Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline

PAZDERSKI, Leszek, Edward SZLYK, Jerzy SITKOWSKI, Bohdan KAMIENSKI, Lech KOZERSKI et. al.

Basic information

Original name

Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline

Name in Czech

Experimentální a kvantově chemická studie N-15 NMR koordinačních posunů v komplexech palladia a platiny s pyridinem, 2,2'-bipyridinem a 1,10-phenantrolinem

Authors

PAZDERSKI, Leszek (616 Poland), Edward SZLYK (616 Poland), Jerzy SITKOWSKI (616 Poland), Bohdan KAMIENSKI (616 Poland), Lech KOZERSKI (616 Poland), Jaromír TOUŠEK (203 Czech Republic, guarantor, belonging to the institution) and Radek MAREK (203 Czech Republic, belonging to the institution)

Edition

Magnetic Resonance in Chemistry, Wiley, 2006, 0749-1581

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10403 Physical chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

DOI: 10.1002/mrc.1740

Impact factor

Impact factor: 1.610

RIV identification code

RIV/00216224:14310/06:00025552

Organization unit

Faculty of Science

DOI

http://dx.doi.org/10.1002/mrc.1740

UT WoS

000235143700010

Keywords in English

NMR; Quantum chemical calculations

Abstract

ORIG CZ

V originále

A series of Pd and Pt chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen), of general formulae trans-/cis-[M(pY)(2)Cl-2], [M(py)(4)]Cl-2, trans-/cis-[M(py)(2)Cl-4], [M(bpy)Cl-2], [M(bPy)Cl-4], [M(phen)Cl-2], [M(phen)Cl-4], where M = Pd, Pt, was studied by H-1, Pt-195, and N-15 NMR. The 90-140 ppm low-frequency N-15 coordination shifts are discussed in terms of such structural features of the complexes as the type of platinide metal, oxidation state, coordination sphere geometry and the type of ligand. The results of quantum-chemical NMR calculations were compared with the experimental N-15 coordination shifts, well reproducing their magnitude and correlation with the molecular structure.

In Czech

Byly studovány NMR koordinační posuny v komplexech palladia a platiny s pyridinem, 2,2'-bipyridinem a 1,10-phenantrolinem.

Links

MSM0021622410, plan (intention)

Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur

Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures

MSM0021622413, plan (intention)

Name: Proteiny v metabolismu a při interakci organismů s prostředím

Investor: Ministry of Education, Youth and Sports of the CR, Proteins in metabolism and interaction of organisms with the environment

Citovat

PAZDERSKI, Leszek, Edward SZLYK, Jerzy SITKOWSKI, Bohdan KAMIENSKI, Lech KOZERSKI, Jaromír TOUŠEK and Radek MAREK. Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline. Magnetic Resonance in Chemistry. Wiley, 2006, vol. 2006, No 1, p. 163-170. ISSN 0749-1581. Available from: https://dx.doi.org/10.1002/mrc.1740.

@article{634212,
   author = {Pazderski, Leszek and Szlyk, Edward and Sitkowski, Jerzy and Kamienski, Bohdan and Kozerski, Lech and Toušek, Jaromír and Marek, Radek},
   article_number = {1},
   doi = {http://dx.doi.org/10.1002/mrc.1740},
   keywords = {NMR; Quantum chemical calculations},
   language = {eng},
   issn = {0749-1581},
   journal = {Magnetic Resonance in Chemistry},
   title = {Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline},
   url = {http://dx.doi.org/10.1002/mrc.1740},
   volume = {2006},
   year = {2006}
}

TY  - JOUR
ID  - 634212
AU  - Pazderski, Leszek - Szlyk, Edward - Sitkowski, Jerzy - Kamienski, Bohdan - Kozerski, Lech - Toušek, Jaromír - Marek, Radek
PY  - 2006
TI  - Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline
JF  - Magnetic Resonance in Chemistry
VL  - 2006
IS  - 1
SP  - 163-170
EP  - 163-170
PB  - Wiley
SN  - 07491581
KW  - NMR
KW  - Quantum chemical calculations
UR  - http://dx.doi.org/10.1002/mrc.1740
L2  - http://dx.doi.org/10.1002/mrc.1740
N2  - A series of Pd and Pt chloride complexes with pyridine (py), 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen), of general formulae trans-/cis-[M(pY)(2)Cl-2], [M(py)(4)]Cl-2, trans-/cis-[M(py)(2)Cl-4], [M(bpy)Cl-2], [M(bPy)Cl-4], [M(phen)Cl-2], [M(phen)Cl-4], where M = Pd, Pt, was studied by H-1, Pt-195, and N-15 NMR. The 90-140 ppm low-frequency N-15 coordination shifts are discussed in terms of such structural features of the complexes as the type of platinide metal, oxidation state, coordination sphere geometry and the type of ligand. The results of quantum-chemical NMR calculations were compared with the experimental N-15 coordination shifts, well reproducing their magnitude and correlation with the molecular structure.
ER  -

PAZDERSKI, Leszek, Edward SZLYK, Jerzy SITKOWSKI, Bohdan KAMIENSKI, Lech KOZERSKI, Jaromír TOUŠEK and Radek MAREK. Experimental and quantum-chemical studies of N-15 NMR coordination shifts in palladium and platinum chloride complexes with pyridine, 2,2 '-bipyridine and 1,10-phenanthroline. \textit{Magnetic Resonance in Chemistry}. Wiley, 2006, vol.~2006, No~1, p.~163-170. ISSN~0749-1581. Available from: https://dx.doi.org/10.1002/mrc.1740.

Detailed Information on Publication Record