| DUBROKA, Adam, Josef HUMLÍČEK, Miroslav Vergilov ABRASHEV, Zoran POPOVIC, Fernando SAPINA and Andres CANTARERO. Raman and infrared studies of La1-ySryMn1-xMxO3 (M=Cr, Co, Cu, Zn, Sc or Ga): Oxygen disorder and local vibrational modes. Physical Review B. USA: The American Physical Society, 2006, vol. 73, No 22, p. 224401-1 do 22440-10, 10 pp. ISSN 1098-0121. |
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@article{637127,
author = {Dubroka, Adam and Humlíček, Josef and Abrashev, Miroslav Vergilov and Popovic, Zoran and Sapina, Fernando and Cantarero, Andres},
article_location = {USA},
article_number = {22},
keywords = {Raman scattering; infrared spectroscopy; La1-xSrxMnO3; Mn substitution; oxygen disorder; local modes},
language = {eng},
issn = {1098-0121},
journal = {Physical Review B},
title = {Raman and infrared studies of La1-ySryMn1-xMxO3 (M=Cr, Co, Cu, Zn, Sc or Ga): Oxygen disorder and local vibrational modes},
volume = {73},
year = {2006}
}
TY - JOUR
ID - 637127
AU - Dubroka, Adam - Humlíček, Josef - Abrashev, Miroslav Vergilov - Popovic, Zoran - Sapina, Fernando - Cantarero, Andres
PY - 2006
TI - Raman and infrared studies of La1-ySryMn1-xMxO3 (M=Cr, Co, Cu, Zn, Sc or Ga): Oxygen disorder and local vibrational modes
JF - Physical Review B
VL - 73
IS - 22
SP - 224401-1 do 22440-10
EP - 224401-1 do 22440-10
PB - The American Physical Society
SN - 10980121
KW - Raman scattering
KW - infrared spectroscopy
KW - La1-xSrxMnO3
KW - Mn substitution
KW - oxygen disorder
KW - local modes
N2 - We present results of our study of polarized Raman scattering and infrared reflectivity of rhombohedral ceramic La1-ySryMn1-xMxO3 manganites in the temperature range between 77 and 320 K. In our samples, a part of the Mn atoms is substituted by M = Cr, Co, Cu, Zn, Sc, or Ga with x in the range 0-0.1. The hole concentration was kept at the optimal value of about 32% by tuning the Sr content y. We have monitored distortions of the oxygen sublattice by the presence of broad bands in the Raman spectra, the increase of dc resistivity extracted from the infrared reflectivity, and the change of the critical temperature of the ferromagnetic transition. Our results support the idea that these properties are mainly determined by the radius of the substituent ion, its electronic and magnetic structure playing only a minor role. Furthermore, the Raman spectra exhibit an additional Ag-like high frequency mode attributed to the local breathing vibration of oxygens surrounding the substituent ion.
ER -
DUBROKA, Adam, Josef HUMLÍČEK, Miroslav Vergilov ABRASHEV, Zoran POPOVIC, Fernando SAPINA and Andres CANTARERO. Raman and infrared studies of La1-ySryMn1-xMxO3 (M=Cr, Co, Cu, Zn, Sc or Ga): Oxygen disorder and local vibrational modes. \textit{Physical Review B}. USA: The American Physical Society, 2006, vol.~73, No~22, p.~224401-1 do 22440-10, 10 pp. ISSN~1098-0121.
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