Detailed Information on Publication Record
2006
Revision of the Structure of Escholidine
CHUDÍK, Stanislav, Radek MAREK, Pavlína SEČKÁŘOVÁ, Marek NEČAS, Jiří DOSTÁL et. al.Basic information
Original name
Revision of the Structure of Escholidine
Name in Czech
Revize struktury escholidinu
Authors
CHUDÍK, Stanislav (203 Czech Republic), Radek MAREK (203 Czech Republic, guarantor), Pavlína SEČKÁŘOVÁ (203 Czech Republic), Marek NEČAS (203 Czech Republic), Jiří DOSTÁL (203 Czech Republic) and Jiří SLAVÍK (203 Czech Republic)
Edition
Journal of Natural Products, Washington, American Chemical Society, 2006, 0163-3864
Other information
Language
English
Type of outcome
Článek v odborném periodiku
Field of Study
10401 Organic chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 2.418
RIV identification code
RIV/00216224:14310/06:00016909
Organization unit
Faculty of Science
UT WoS
000238478800017
Keywords in English
alkaloid; escholidine; NMR; X-ray
Tags
Tags
International impact, Reviewed
Změněno: 1/4/2010 06:25, doc. RNDr. Jiří Dostál, CSc.
V originále
The structure of the quaternary tetrahydroprotoberberine alkaloid escholidine is revised on the basis of 2D NMR spectroscopy and X-ray diffraction. In contrast to the originally reported constitution, escholidine bears an -OH group at C-9 and an -OCH3 group at C-10. The 1H and 13C NMR data and long-range 1H-13C and NOE interactions of escholidine are compared with those of thalifendine and tetrahydroberberrubine. The 15N NMR data of escholidine obtained by using long-range 1H-15N correlation experiments at natural abundance are also reported.
In Czech
Struktura kvartérního protoberberinového alkaloidu escholidinu je revidována na základě 2D NMR spektroskopie a rentgenové difrakce. Na rozdíl od původně publikované konstituce má escholidin -OH skupinu na C-9 a -OCH3 skupinu na C-10.
Links
| LC06030, research and development project |
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| MSM0021622413, plan (intention) |
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