| KRATOCHVÍL, Jan, Marek NEČAS, Václav PETŘÍČEK a Jiří PINKAS. Cubic octanuclear aluminum fluoride phosphonate. INORGANIC CHEMISTRY. Spojené státy americké: American Chemical Society, Washington DC, 2006, roč. 45, č. 17, s. 6562-6564. ISSN 0020-1669. |
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@article{694467,
author = {Kratochvíl, Jan and Nečas, Marek and Petříček, Václav and Pinkas, Jiří},
article_location = {Spojené státy americké},
article_number = {17},
keywords = {aluminum; fluoride; phosphonate; D4R},
language = {eng},
issn = {0020-1669},
journal = {INORGANIC CHEMISTRY},
title = {Cubic octanuclear aluminum fluoride phosphonate},
volume = {45},
year = {2006}
}
TY - JOUR
ID - 694467
AU - Kratochvíl, Jan - Nečas, Marek - Petříček, Václav - Pinkas, Jiří
PY - 2006
TI - Cubic octanuclear aluminum fluoride phosphonate
JF - INORGANIC CHEMISTRY
VL - 45
IS - 17
SP - 6562-6564
EP - 6562-6564
PB - American Chemical Society, Washington DC
SN - 00201669
KW - aluminum
KW - fluoride
KW - phosphonate
KW - D4R
N2 - A crystalline complex [Al8F12{(CH3)2C(NH3)PO3}12] (1) was isolated from the supernatant of the hydrothermal reaction of gibbsite Al- (OH)3 with 1-amino-1-methyl-ethylphosphonic acid (AIPA) and the HF mineralizer. The single-crystal X-ray diffraction analysis revealed a highly symmetrical cubic Al8F12 core with aluminum atoms at the corners, bridging fluorides spanning all edges, and 12 bidentate bridging phosphonate ligands completing the octahedral coordination sphere of aluminum centers. The stability of the complex in solution was established by electrospray mass spectrometry and the high molecular symmetry ( Th) was reflected in the appearance of single resonances in the 1H, 19F, and 31P NMR spectra.
ER -
KRATOCHVÍL, Jan, Marek NEČAS, Václav PETŘÍČEK a Jiří PINKAS. Cubic octanuclear aluminum fluoride phosphonate. \textit{INORGANIC CHEMISTRY}. Spojené státy americké: American Chemical Society, Washington DC, 2006, roč.~45, č.~17, s.~6562-6564. ISSN~0020-1669.
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