KRATOCHVÍL, Jan, Marek NEČAS, Václav PETŘÍČEK and Jiří PINKAS. Cubic octanuclear aluminum fluoride phosphonate. INORGANIC CHEMISTRY. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol. 45, No 17, p. 6562-6564. ISSN 0020-1669. |
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@article{694467, author = {Kratochvíl, Jan and Nečas, Marek and Petříček, Václav and Pinkas, Jiří}, article_location = {Spojené státy americké}, article_number = {17}, keywords = {aluminum; fluoride; phosphonate; D4R}, language = {eng}, issn = {0020-1669}, journal = {INORGANIC CHEMISTRY}, title = {Cubic octanuclear aluminum fluoride phosphonate}, volume = {45}, year = {2006} }
TY - JOUR ID - 694467 AU - Kratochvíl, Jan - Nečas, Marek - Petříček, Václav - Pinkas, Jiří PY - 2006 TI - Cubic octanuclear aluminum fluoride phosphonate JF - INORGANIC CHEMISTRY VL - 45 IS - 17 SP - 6562-6564 EP - 6562-6564 PB - American Chemical Society, Washington DC SN - 00201669 KW - aluminum KW - fluoride KW - phosphonate KW - D4R N2 - A crystalline complex [Al8F12{(CH3)2C(NH3)PO3}12] (1) was isolated from the supernatant of the hydrothermal reaction of gibbsite Al- (OH)3 with 1-amino-1-methyl-ethylphosphonic acid (AIPA) and the HF mineralizer. The single-crystal X-ray diffraction analysis revealed a highly symmetrical cubic Al8F12 core with aluminum atoms at the corners, bridging fluorides spanning all edges, and 12 bidentate bridging phosphonate ligands completing the octahedral coordination sphere of aluminum centers. The stability of the complex in solution was established by electrospray mass spectrometry and the high molecular symmetry ( Th) was reflected in the appearance of single resonances in the 1H, 19F, and 31P NMR spectra. ER -
KRATOCHVÍL, Jan, Marek NEČAS, Václav PETŘÍČEK and Jiří PINKAS. Cubic octanuclear aluminum fluoride phosphonate. \textit{INORGANIC CHEMISTRY}. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol.~45, No~17, p.~6562-6564. ISSN~0020-1669.
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