LÖBL, Jiří, Jiří PINKAS, Herbert W. ROESKY, Winfried PLASS and Helmar GÖRLS. A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate. INORGANIC CHEMISTRY. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol. 45, No 17, p. 6571-6573. ISSN 0020-1669. |
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@article{694468, author = {Löbl, Jiří and Pinkas, Jiří and Roesky, Herbert W. and Plass, Winfried and Görls, Helmar}, article_location = {Spojené státy americké}, article_number = {17}, keywords = {dealkylsilylation; alumazene; methylsulfonate}, language = {eng}, issn = {0020-1669}, journal = {INORGANIC CHEMISTRY}, title = {A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate}, volume = {45}, year = {2006} }
TY - JOUR ID - 694468 AU - Löbl, Jiří - Pinkas, Jiří - Roesky, Herbert W. - Plass, Winfried - Görls, Helmar PY - 2006 TI - A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate JF - INORGANIC CHEMISTRY VL - 45 IS - 17 SP - 6571-6573 EP - 6571-6573 PB - American Chemical Society, Washington DC SN - 00201669 KW - dealkylsilylation KW - alumazene KW - methylsulfonate N2 - A dealkylsilylation reaction of alumazene [2,6-( i-Pr)2C6H3NAlMe]3 (1) with trimethylsilyl methylsulfonate in a 1:2 molar ratio in toluene afforded a supramolecular cyclic hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2) composed of six intact alumazene rings and possessing two types of bridging sulfonate groups. Changing the reagent molar ratio to 1:3 caused the third sulfonate to partially substitute the last alumazene methyl group in an eta2 fashion and introduced a disorder in the crystal lattice. ER -
LÖBL, Jiří, Jiří PINKAS, Herbert W. ROESKY, Winfried PLASS and Helmar GÖRLS. A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate. \textit{INORGANIC CHEMISTRY}. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol.~45, No~17, p.~6571-6573. ISSN~0020-1669.
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