| LÖBL, Jiří, Jiří PINKAS, Herbert W. ROESKY, Winfried PLASS and Helmar GÖRLS. A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate. INORGANIC CHEMISTRY. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol. 45, No 17, p. 6571-6573. ISSN 0020-1669. |
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@article{694468,
author = {Löbl, Jiří and Pinkas, Jiří and Roesky, Herbert W. and Plass, Winfried and Görls, Helmar},
article_location = {Spojené státy americké},
article_number = {17},
keywords = {dealkylsilylation; alumazene; methylsulfonate},
language = {eng},
issn = {0020-1669},
journal = {INORGANIC CHEMISTRY},
title = {A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate},
volume = {45},
year = {2006}
}
TY - JOUR
ID - 694468
AU - Löbl, Jiří - Pinkas, Jiří - Roesky, Herbert W. - Plass, Winfried - Görls, Helmar
PY - 2006
TI - A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate
JF - INORGANIC CHEMISTRY
VL - 45
IS - 17
SP - 6571-6573
EP - 6571-6573
PB - American Chemical Society, Washington DC
SN - 00201669
KW - dealkylsilylation
KW - alumazene
KW - methylsulfonate
N2 - A dealkylsilylation reaction of alumazene [2,6-( i-Pr)2C6H3NAlMe]3 (1) with trimethylsilyl methylsulfonate in a 1:2 molar ratio in toluene afforded a supramolecular cyclic hexamer {Me[2,6-( i-Pr)2C6H3NAl]3- (O3SMe)2}6 (2) composed of six intact alumazene rings and possessing two types of bridging sulfonate groups. Changing the reagent molar ratio to 1:3 caused the third sulfonate to partially substitute the last alumazene methyl group in an eta2 fashion and introduced a disorder in the crystal lattice.
ER -
LÖBL, Jiří, Jiří PINKAS, Herbert W. ROESKY, Winfried PLASS and Helmar GÖRLS. A Supramolecular Hexameric Ring from Alumazene and Methylsulfonate. \textit{INORGANIC CHEMISTRY}. Spojené státy americké: American Chemical Society, Washington DC, 2006, vol.~45, No~17, p.~6571-6573. ISSN~0020-1669.
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