D 2006

Alumazene in dealkylsilylation reactions with E-O-SiMe3 compounds

PINKAS, Jiří, Jiří LÖBL and Marek NEČAS

Basic information

Original name

Alumazene in dealkylsilylation reactions with E-O-SiMe3 compounds

Name in Czech

Dealkylsilylační reakce alumazenu se sloučeninami E-O-SiMe3

Authors

Edition

1. vyd. Oulu, Finland, 11th International Symposium on Inorganic Ring Systems, p. 25-25, 2006

Publisher

University of Oulu, Oulu, Finland

Other information

Language

English

Type of outcome

Stať ve sborníku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

Finland

Confidentiality degree

není předmětem státního či obchodního tajemství

Organization unit

Faculty of Science

ISBN

951-42-8153-5

Keywords in English

Alumazene; dealkylsilylation; phosphonates;

Tags

Změněno: 31/5/2009 22:21, prof. RNDr. Jiří Pinkas, Ph.D.

Abstract

ORIG CZ

V originále

Alumazene, [2,6-(i-Pr)2C6H3NAlMe]3, is the only known trimeric iminoalane. Its high reactivity stems from the polar Al-N bonds and a low delocalization of the pi electrons in the ring. We studied the mild dealkylsilylation reaction of alumazene with a variety of trimethylsiloxy compounds of silicon, phosphorus, and sulfur with the aim of obtaining new polycyclic and polyhedral derivatives. During these studies we also prepared adducts of phosphine oxides and other Lewis bases with alumazene and established their molecular structures.

In Czech

Dealkylsilylační reakce alumazenu se sloučeninami E-O-SiMe3

Links

GA203/04/0296, research and development project
Name: Sonochemická syntéza oxidových a fosfátových materiálů
Investor: Czech Science Foundation, Sonochemical Synthesis of Oxide and Phosphate Materials
MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures