| MOŽNÁ, Veronika, Jorge PISONERO, Markéta HOLÁ, Viktor KANICKÝ and Detlef GUNTHER. Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS. Journal of Analytical Atomic Spectrometry. Cambridge: Royal Society of Chemistry, 2006, 21/2006, No 11, p. 1194-1201, 10 pp. ISSN 0267-9477. |
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@article{708248,
author = {Možná, Veronika and Pisonero, Jorge and Holá, Markéta and Kanický, Viktor and Gunther, Detlef},
article_location = {Cambridge},
article_number = {11},
keywords = {INDUCTIVELY-COUPLED PLASMA; PARTICLE-SIZE DISTRIBUTION; ELEMENTAL RESPONSE VARIATIONS; MATRIX MATCHED CALIBRATION; NEAR-IR FEMTOSECOND; MASS SPECTROMETRY; GENERATED AEROSOLS; FRACTIONATION; BRASS; GLASS},
language = {eng},
issn = {0267-9477},
journal = {Journal of Analytical Atomic Spectrometry},
title = {Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS},
volume = {21/2006},
year = {2006}
}
TY - JOUR
ID - 708248
AU - Možná, Veronika - Pisonero, Jorge - Holá, Markéta - Kanický, Viktor - Gunther, Detlef
PY - 2006
TI - Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS
JF - Journal of Analytical Atomic Spectrometry
VL - 21/2006
IS - 11
SP - 1194-1201
EP - 1194-1201
PB - Royal Society of Chemistry
SN - 02679477
KW - INDUCTIVELY-COUPLED PLASMA
KW - PARTICLE-SIZE DISTRIBUTION
KW - ELEMENTAL RESPONSE VARIATIONS
KW - MATRIX MATCHED CALIBRATION
KW - NEAR-IR FEMTOSECOND
KW - MASS SPECTROMETRY
KW - GENERATED AEROSOLS
KW - FRACTIONATION
KW - BRASS
KW - GLASS
N2 - The quantification capabilities of iron-based samples were investigated using three commercially available ultraviolet (UV) nanosecond (ns) and femtosecond ( fs) laser ablation systems coupled to inductively coupled plasma mass spectrometry ( LA- ICP- MS). A comparison of three pulsed laser ablation systems ( ArF* excimer, Nd: YAG and Ti- sapphire) with different wavelengths and pulse time durations ( 15 ns, 4 ns and 150 fs, respectively) was performed. Minor and trace elements were determined using 57 Fe as internal standard element. Using similar spatial resolution for all laser systems and commonly applied operating conditions for each system, higher ion-signals ( 25 - 30%) and more stable elemental ratios ( 10% TRSD) were obtained for UV- fs- LA- ICP- MS. Scanning electron microscope images and particle size distributions measured for UV- ns- LA systems showed a bimodal distribution formed by nano- sized agglomerates and micro- sized molten spherical particles. In contrast, due to reduced thermal effects achieved using ultra-short pulses, the particle size distribution measured using UV- fs- LA showed a broad monomodal distribution ( nano- sized agglomerates in the range of 50 - 250 nm). Matrix- matched ( within metallic samples) and non- matrix matched calibrations were applied for the analysis of Fe- based samples, using a silicate glass ( SRM NIST 610) as non- matrix matched calibration sample ( glassmetals). Improved analytical results in terms of precision and accuracy were obtained using femtosecond laser ablation when using similar matrices for calibration. Moreover, non- matrix matched calibration used for quanti. cation provides more accurate results ( 5 - 15%) in comparison with both UV- ns- LA- ICP- MS ( 5 - 30% using Nd: YAG laser and 15 - 60% using ArF* laser).
ER -
MOŽNÁ, Veronika, Jorge PISONERO, Markéta HOLÁ, Viktor KANICKÝ and Detlef GUNTHER. Quantitative analysis of Fe-based samples using ultraviolet nanosecond and femtosecond laser ablation-ICP-MS. \textit{Journal of Analytical Atomic Spectrometry}. Cambridge: Royal Society of Chemistry, 2006, 21/2006, No~11, p.~1194-1201, 10 pp. ISSN~0267-9477.
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