MAREK, Jaromír, Zdeněk TRÁVNÍČEK and Šárka ČERMÁKOVÁ. (N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II). Acta Crystallographica Section E: Structure Reports Online. Structure Reports Oline, vol. 63, No 3, p. m725-m727, 3 pp. ISSN 1600-5368. 2007.
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Basic information
Original name (N,N,N',N'',N''-Pentamethyldiethylenetriamine-[kappa]3N,N',N'')(trithiocyanurato-[kappa]2N,S)zinc(II)
Name in Czech Krystalová struktura pentamethyldiethylentriamino-trithiocyanurato- zinečnatého komplexu
Authors MAREK, Jaromír (203 Czech Republic, guarantor), Zdeněk TRÁVNÍČEK (203 Czech Republic) and Šárka ČERMÁKOVÁ (203 Czech Republic).
Edition Acta Crystallographica Section E: Structure Reports Online, Structure Reports Oline, 2007, 1600-5368.
Other information
Original language English
Type of outcome Article in a journal
Field of Study 10402 Inorganic and nuclear chemistry
Country of publisher United Kingdom of Great Britain and Northern Ireland
Confidentiality degree is not subject to a state or trade secret
Impact factor Impact factor: 0.508
RIV identification code RIV/00216224:14310/07:00021953
Organization unit Faculty of Science
UT WoS 000245434500045
Keywords in English Zinc(II); trithiocyanuric acid; structure;
Tags structure, trithiocyanuric acid, zinc(II)
Tags Reviewed
Changed by Changed by: doc. RNDr. Jaromír Marek, Ph.D., učo 1989. Changed: 2/3/2007 17:02.
Abstract
The structure of the title compound, [Zn(C9H23N3)(C3HN3S3)], consists of discrete molecules connected by N-H...S hydrogen bonds into centrosymmetric dimers. The ZnII atom is pentacoordinated in a deformed trigonal-bipyramidal geometry by three N atoms of a tridentate N,N,N',N'',N''-pentamethyldiethylenetriamine ligand, and one S and one N atoms of a trithiocyanurate dianion bonded as a bidentate ligand. The crystal structure is further stabilized by close contacts of the types C-H...S and C-H...N.
Abstract (in Czech)
Struktura titulního komplexu, [Zn(C9H23N3)(C3HN3S3)], se skládá z molekul spojených N-H...S vodíkovými můstky do formy centrosymetrických dimerů. Atom Zn(II) je 5x koordinovaný. Jeho koordinační okolí je možné popsat jako deformovanou trojbokou bipyramidu definovanou 3 N atomy pentamethyldiethylenetriaminu a jedním atomem S a jedním atomem N z trithiocyanurového dianionu působícího jako bidentátní ligand. Struktura je dále stabilizovaná nevazebnými kontakty typu C-H...S a C-H...N.
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