J 2007

Deposition of protective coatings in rf organosilicon discharges

ZAJÍČKOVÁ, Lenka, Vilma BURŠÍKOVÁ, Zuzana KUČEROVÁ, Daniel FRANTA, Pavel DVOŘÁK et. al.

Basic information

Original name

Deposition of protective coatings in rf organosilicon discharges

Name in Czech

Depozice ochranných vrstev ve vysokofrekvenčních výbojích v parách organosilikonu

Authors

ZAJÍČKOVÁ, Lenka (203 Czech Republic, guarantor), Vilma BURŠÍKOVÁ (203 Czech Republic), Zuzana KUČEROVÁ (203 Czech Republic), Daniel FRANTA (203 Czech Republic), Pavel DVOŘÁK (203 Czech Republic), Radek ŠMÍD (203 Czech Republic), Vratislav PEŘINA (203 Czech Republic) and Anna MACKOVÁ (203 Czech Republic)

Edition

Plasma Sources Science and Technology, Bristol, Institute of Physics Publishing, 2007, 0963-0252

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10305 Fluids and plasma physics

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.120

RIV identification code

RIV/00216224:14310/07:00022271

Organization unit

Faculty of Science

UT WoS

000244370700016

Keywords in English

CARBON-FILMS; GLOW-DISCHARGES; PLASMA; PECVD; POLYCARBONATE; SUBSTRATE

Tags

International impact, Reviewed
Změněno: 3/1/2011 11:26, doc. Mgr. Pavel Dvořák, Ph.D.

Abstract

V originále

The paper discusses the deposition of protective coatings ranging from organosilicon plasma polymers to SiO2-like films and hard diamond-like carbon/silicon oxide (DLC : SiOx) coatings in radio frequency capacitively coupled discharges using hexamethyldisiloxane (HMDSO). As a result of the optimization of the deposition conditions it was possible to obtain high performance protective coatings. In the HMDSO/O-2 mixture, it was shown that rather than the SiO2-like film a hard cross-linked SiOx C-y H-z polymer film can be used as a protective coating for polycarbonate. The optimum conditions for the deposition of an almost stress-free film were 17% of HMDSO and dc bias voltage of -240V. The film hardness and elastic modulus were 10GPa and 75GPa, respectively. The refractive index at 600 nm was 1.5 and the extinction coefficient decreased from 0.02 at 240 nm down to zero at 600 nm. The films deposited from HMDSO/CH4 and HMDSO/CH4/H-2 mixtures exhibited the attractive properties of DLC films with the partial elimination of some of their drawbacks, such as absorption in the visible and a high intrinsic stress. The optimum concentration of the HMDSO was approximately 21%. Under these conditions the concentration of SiOx in the films was approximately 9 at.%. The film hardness and elastic modulus were above 22 GPa and 120 GPa, respectively.

In Czech

Článek diskutuje depozici různých typů ochranných vrstev, organosilikonových plazmových polymerů, SiO2 vrstev a tvrdých uhlíkových diamantu podobných vrstev s obsahem SiOx (DLC:SiOx), ve vysokofrekvenčním kapacitně vázaném výboji s použitím hexametyldisiloxanu (HMDSO). Vrstvy připravené z HMDSO/CH4 a HMDSO/CH4/H2 směsí vykazovaly atraktivní vlastnosti DLC vrstev s částečným optlačením jejich některých nevýhod jako jsou absorpce ve viditelné oblasti a vysoké vnitřní pnutí.

Links

MSM0021622411, plan (intention)
Name: Studium a aplikace plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek
Investor: Ministry of Education, Youth and Sports of the CR, Study and application of plasma chemical reactions in non-isothermic low temperature plasma and its interaction with solid surface
1K05025, research and development project
Name: Příprava nových Si-O(N)-C materiálů plazmochemickou metodou
Investor: Ministry of Education, Youth and Sports of the CR, Synthesis of new Si-O(N)-C materials by plasmachemical methods