| PINKAS, Jiří, Vendula REICHLOVÁ, Radek ZBOŘIL, Zdeněk MORAVEC, Petr BEZDIČKA and Jiřina MATEJKOVÁ. Sonochemical synthesis of amorphous nanoscopic iron(III) oxide from Fe(acac)3. Ultrasonics Sonochemistry. Elsevier, 2008, vol. 15, No 3, p. 257-264. ISSN 1350-4177. |
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@article{727562,
author = {Pinkas, Jiří and Reichlová, Vendula and Zbořil, Radek and Moravec, Zdeněk and Bezdička, Petr and Matejková, Jiřina},
article_number = {3},
keywords = {Sonochemistry; Iron; Oxides; Nanoparticles},
language = {eng},
issn = {1350-4177},
journal = {Ultrasonics Sonochemistry},
title = {Sonochemical synthesis of amorphous nanoscopic iron(III) oxide from Fe(acac)3},
volume = {15},
year = {2008}
}
TY - JOUR
ID - 727562
AU - Pinkas, Jiří - Reichlová, Vendula - Zbořil, Radek - Moravec, Zdeněk - Bezdička, Petr - Matejková, Jiřina
PY - 2008
TI - Sonochemical synthesis of amorphous nanoscopic iron(III) oxide from Fe(acac)3
JF - Ultrasonics Sonochemistry
VL - 15
IS - 3
SP - 257-264
EP - 257-264
PB - Elsevier
SN - 13504177
KW - Sonochemistry
KW - Iron
KW - Oxides
KW - Nanoparticles
N2 - Amorphous nanoscopic iron(III) oxide with interesting magnetic properties was prepared by sonolysis of Fe(acac)3 under Ar in tetraglyme with a small amount of added water. The organics content and the surface area of the Fe2O3 nanoparticles can be controlled with an amount of water in the reaction mixture and it increases from 48 m2 g-1 for dry solvent up to 260 m2 g-1 when wet Ar is employed. For further monitoring of the particle size and morphology and for the study of the surface, magnetic and thermal properties, the sample with 2 vol.% of H2O was chosen. SEM showed nanoscopic composite particles of a uniform size distribution and nearly spherical shapes with an estimated diameter of 20 nm. Such composites are built from amorphous iron(III) oxide nanoparticles (3 nm) embedded in an acetate matrix as proved by TEM and IR spectroscopy. Temperature-dependent Moessbauer spectra demonstrate a very narrow magnetic transition with an unusually low transition temperature around 25 K reflecting the system of magnetically noninteracting ultrasmall particles with a narrow size distribution. The in-field (5 T) Moessbauer spectrum recorded at 5 K shows a minimum change compared to the zero-field spectrum indicating an absence of the long-range magnetic ordering. The composite particles are thermally stable up to 150 oC, which is confirmed by DSC, TG, and by the constant surface area. At higher temperatures, acetate groups are removed from the particle surface, which is documented by the increased surface area and disappearance of their IR bands.
ER -
PINKAS, Jiří, Vendula REICHLOVÁ, Radek ZBOŘIL, Zdeněk MORAVEC, Petr BEZDIČKA and Jiřina MATEJKOVÁ. Sonochemical synthesis of amorphous nanoscopic iron(III) oxide from Fe(acac)3. \textit{Ultrasonics Sonochemistry}. Elsevier, 2008, vol.~15, No~3, p.~257-264. ISSN~1350-4177.
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