MATULOVÁ, Veronika, Stanislav MAN and Marek NEČAS. Binuclear complexes of 4-methoxyphenyltellurium trichloride with variably linked diphosphine disulfide ligands. Polyhedron. Velká Británie: Elsevier Science Ltd., 2007, vol. 26, No 12, p. 2569-2573. ISSN 0277-5387. |
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@article{744440, author = {Matulová, Veronika and Man, Stanislav and Nečas, Marek}, article_location = {Velká Británie}, article_number = {12}, keywords = {Diphosphine disulfide ligands; Tellurium(IV); Binuclear complexes; Trans-influence; X-ray crystallography}, language = {eng}, issn = {0277-5387}, journal = {Polyhedron}, title = {Binuclear complexes of 4-methoxyphenyltellurium trichloride with variably linked diphosphine disulfide ligands}, volume = {26}, year = {2007} }
TY - JOUR ID - 744440 AU - Matulová, Veronika - Man, Stanislav - Nečas, Marek PY - 2007 TI - Binuclear complexes of 4-methoxyphenyltellurium trichloride with variably linked diphosphine disulfide ligands JF - Polyhedron VL - 26 IS - 12 SP - 2569-2573 EP - 2569-2573 PB - Elsevier Science Ltd. SN - 02775387 KW - Diphosphine disulfide ligands KW - Tellurium(IV) KW - Binuclear complexes KW - Trans-influence KW - X-ray crystallography N2 - Four neutral ligands of the diphosphine disulfide type with different central linking groups [(CH2)4, (CH2)6, (C6H4)2, and HN-(C6H4)-NH] were reacted with 4-methoxyphenyltellurium trichloride in dichloromethane. The crystallization of products afforded crystals consisting of binuclear addition complexes of 4-MeOC6H4TeCl3 with corresponding ligands. The ligands are coordinated to Te(IV) centres through weak Te-S bonds. The coordination of both tellurium atoms in each complex is pseudo-octahedral, built of the TeCl3S tetragonal basis and the aryl group and the lone pair of electrons in axial positions. The weak donating properties of sulfur atoms are reflected in shortening of the trans-positioned Te-Cl bonds. ER -
MATULOVÁ, Veronika, Stanislav MAN and Marek NEČAS. Binuclear complexes of 4-methoxyphenyltellurium trichloride with variably linked diphosphine disulfide ligands. \textit{Polyhedron}. Velká Británie: Elsevier Science Ltd., 2007, vol.~26, No~12, p.~2569-2573. ISSN~0277-5387.
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