J
2007
Surface modification of polycarbonate in homogeneous atmospheric pressure discharge
ŠÍRA, Martin, David TRUNEC, Pavel SŤAHEL, Vilma BURŠÍKOVÁ, Zdeněk NAVRÁTIL et. al.
Basic information
Original name
Surface modification of polycarbonate in homogeneous atmospheric pressure discharge
Name in Czech
Úprava povrchu polykarbonátu v homogenním výboji za atmosférického tlaku
Edition
Journal of Physics D: Applied physics, 2007, 0022-3727
Other information
Type of outcome
Článek v odborném periodiku
Field of Study
10305 Fluids and plasma physics
Country of publisher
United Kingdom of Great Britain and Northern Ireland
Confidentiality degree
není předmětem státního či obchodního tajemství
Impact factor
Impact factor: 2.200
RIV identification code
RIV/00216224:14310/07:00020682
Organization unit
Faculty of Science
Keywords in English
homogeneous atmospheric pressure discharge; polycarbonate; surface free energy
Tags
International impact, Reviewed
V originále
A homogeneous atmospheric pressure dielectric barrier discharge was used for the surface modification of polycarbonate (PC). The discharge was generated between two planar metal electrodes, the top electrode was covered by glass and the bottom electrode was covered by a polymer sample. The discharge burned in pure nitrogen or in a mixture of nitrogen and hydrogen. The surface properties of both treated and untreated polymers were characterized by atomic force microscopy, surface free energy (SFE) measurements and x-ray photoelectron spectroscopy. The influence of the treatment time and power input to the discharge on the surface properties of polymers was studied. The ageing of treated samples was also investigated. The treatment of polymers in the homogeneous atmospheric pressure discharge was homogeneous and the polymer surfaces showed a smaller degree of roughness in comparison with the polymer surfaces treated in a filamentary discharge. The SFE of the treated PC obtained at optimum conditions was 53 mJ cm-2 and the corresponding contact angle of water was 38deg . The maximum decrease in the SFE during ageing was about 13%. The analysis of the chemical composition showed an increase in the nitrogen concentration in the surface layer, but almost a zero increase in the oxygen concentration. This result was discussed concerning the measured values of the SFE measurement.
In Czech
Úprava povrchu polykarbonátu v homogenním výboji za atmosférického tlaku
Links
GA202/06/1473, research and development project | Name: Depozice tenkých vrstev v dielektrických bariérových výbojích za atmosférického tlaku | Investor: Czech Science Foundation, Deposition of thin films in dielectric barrier discharges at atmospheric pressure |
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MSM0021622411, plan (intention) | Name: Studium a aplikace plazmochemických reakcí v neizotermickém nízkoteplotním plazmatu a jeho interakcí s povrchem pevných látek | Investor: Ministry of Education, Youth and Sports of the CR, Study and application of plasma chemical reactions in non-isothermic low temperature plasma and its interaction with solid surface |
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