J 2007

Polymer selection for passive sampling: a comparison of critical properties.

RUSINA, Tatsiana, Foppe SMEDES, Jana KLÁNOVÁ, Kees BOOIJ, Ivan HOLOUBEK et. al.

Basic information

Original name

Polymer selection for passive sampling: a comparison of critical properties.

Name in Czech

Výběr polymerů pro pasivní vzorkování: srovnání kritických vlastností.

Authors

RUSINA, Tatsiana (112 Belarus, guarantor), Foppe SMEDES (528 Netherlands), Jana KLÁNOVÁ (203 Czech Republic), Kees BOOIJ (528 Netherlands) and Ivan HOLOUBEK (203 Czech Republic)

Edition

Chemosphere, Oxford, UK, Elsevier Science Ltd. 2007, 0045-6535

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10511 Environmental sciences

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.739

RIV identification code

RIV/00216224:14310/07:00023688

Organization unit

Faculty of Science

UT WoS

000247580200019

Keywords in English

Single phase material; diffusion coefficient; transport resistence; partitioning coefficient; hydrophobic organic compounds

Tags

International impact, Reviewed
Změněno: 16/7/2008 15:11, Mgr. Petr Bureš

Abstract

V originále

Passive sampling technique has been used successfully for environmental monitoring. Besides the semi-permeable membrane devices (SPMDs), recently the use of single phase materials for passive sampling is becoming more popular. In this research, critical relevant properties of single phase materials including low density polyethylene (LDPE), polyoxymethylene (POM), polydimethylsiloxane (PDMS), other silicone rubbers (SRs) and EXACT polymer were estimated. Diffusion coefficients (D) of Naphthalene (Naph), Fluoranthene (Flu), Benzo(a)pyrene (BaP) and Dibenz(ah)anthracene (DBahA) were measured in all the materials investigated. Other properties that are characteristic for each material (resistance to solvents, glass transition temperature (Tg), release of oligomers, solubility (S) of polycyclic aromatic hydrocarbons (PAHs) in materials, permeability (P)) were evaluated in relation to D. Higher diffusion and permeability was observed in all SRs than in LDPE and EXACT. Therefore, SRs are suitable for use as passive samplers. POM does not seem to be a permeable material.

In Czech

Passive sampling technique has been used successfully for environmental monitoring. Besides the semi-permeable membrane devices (SPMDs), recently the use of single phase materials for passive sampling is becoming more popular. In this research, critical relevant properties of single phase materials including low density polyethylene (LDPE), polyoxymethylene (POM), polydimethylsiloxane (PDMS), other silicone rubbers (SRs) and EXACT polymer were estimated. Diffusion coefficients (D) of Naphthalene (Naph), Fluoranthene (Flu), Benzo(a)pyrene (BaP) and Dibenz(ah)anthracene (DBahA) were measured in all the materials investigated. Other properties that are characteristic for each material (resistance to solvents, glass transition temperature (Tg), release of oligomers, solubility (S) of polycyclic aromatic hydrocarbons (PAHs) in materials, permeability (P)) were evaluated in relation to D. Higher diffusion and permeability was observed in all SRs than in LDPE and EXACT. Therefore, SRs are suitable for use as passive samplers. POM does not seem to be a permeable material.

Links

MSM0021622412, plan (intention)
Name: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Acronym: INCHEMBIOL)
Investor: Ministry of Education, Youth and Sports of the CR, Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)