| PEVEC, Andrej, Alojz DEMSAR, Jiří PINKAS and Marek NEČAS. Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate. Online. Inorganic Chemistry Communication. Amsterdam: Elsevier, 2008, vol. 11, No 1, p. 5-7. ISSN 1387-7003. [citováno 2024-04-24] |
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@article{754957,
author = {Pevec, Andrej and Demsar, Alojz and Pinkas, Jiří and Nečas, Marek},
article_location = {Amsterdam},
article_number = {1},
keywords = {Titanium; Phosphonate; Crystal structure; Hydrogen bond},
language = {eng},
issn = {1387-7003},
journal = {Inorganic Chemistry Communication},
title = {Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate},
volume = {11},
year = {2008}
}
TY - JOUR
ID - 754957
AU - Pevec, Andrej - Demsar, Alojz - Pinkas, Jiří - Nečas, Marek
PY - 2008
TI - Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate
JF - Inorganic Chemistry Communication
VL - 11
IS - 1
SP - 5-7
EP - 5-7
PB - Elsevier
SN - 13877003
KW - Titanium
KW - Phosphonate
KW - Crystal structure
KW - Hydrogen bond
N2 - Dititanate [{Ti(C5Me4Et)(O2P(OH)Me)(O2P(O)Me)}2] (1) was prepared from (C5Me4Et)TiF3 and MeP(O)(OSiMe3)2. The molecular structure of the compound 1 has been determined by single-crystal X-ray diffraction analysis. In the cage cluster, two titanium atoms are bridged by two bidentate monoanionic and by two bidentate dianionic methylphosphonate groups. The OH groups of the monoanionic phosphonates and oxygen atoms of the dianionic phosphonates are connected by strong intramolecular hydrogen bonds. The NMR spectroscopy reveals the fast proton migration within the hydrogen bond.
ER -
PEVEC, Andrej, Alojz DEMSAR, Jiří PINKAS and Marek NEČAS. Synthesis, spectroscopic and X-ray characterization of new molecular organotitanium(IV) phosphonate. Online. \textit{Inorganic Chemistry Communication}. Amsterdam: Elsevier, 2008, vol.~11, No~1, p.~5-7. ISSN~1387-7003. [citováno 2024-04-24]
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