13C CHEMICAL SHIFT TENSORS IN REGIOISOMERS OF N-SUBSTITUTED ADENINES
| MALIŇÁKOVÁ, Kateřina, Stanislav STANDARA and Radek MAREK. 13C CHEMICAL SHIFT TENSORS IN REGIOISOMERS OF N-SUBSTITUTED ADENINES. In 23rd NMR Valtice. 2008. ISBN 978-80-86441-39-9. |
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| Basic information | |
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| Original name | 13C CHEMICAL SHIFT TENSORS IN REGIOISOMERS OF N-SUBSTITUTED ADENINES |
| Name in Czech | Tenzory chemického posunu uhlíku 13C v regioizomerech substituovaných adeninů |
| Authors | MALIŇÁKOVÁ, Kateřina (203 Czech Republic), Stanislav STANDARA (203 Czech Republic) and Radek MAREK (203 Czech Republic, guarantor). |
| Edition | 23rd NMR Valtice, 2008. |
| Other information | |
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| Original language | English |
| Type of outcome | Conference abstract |
| Field of Study | 10403 Physical chemistry |
| Country of publisher | Czech Republic |
| Confidentiality degree | is not subject to a state or trade secret |
| RIV identification code | RIV/00216224:14310/08:00025914 |
| Organization unit | Faculty of Science |
| ISBN | 978-80-86441-39-9 |
| Keywords in English | adenine; regioisomers; 13C chemical shift tensors |
| Tags | 13C chemical shift tensors, adenine, regioisomers |
| Changed by | Changed by: prof. RNDr. Radek Marek, Ph.D., učo 381. Changed: 9/4/2010 17:29. |
| Abstract |
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| Solid state NMR spectroscopy was utilized to study three regioisomers of N-benzylated adenine. Slow-spinning CP/MAS experiment was performed and chemical shift tensor principal values for nucleobase carbons were extracted. Orientations of the principal components in the molecular frame were determined with the use of DFT calculations. Results for the three regioisomers were compared and the differences described. |
| Abstract (in Czech) |
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| Metodami NMR spektroskopie v pevné fázi byly studovány tři regioizomery N-benzylovaného adeninu. Z CP/MAS experimentu s pomalou rotací vzorku byly extrahovány hlavní složky tenzoru chemického posunu pro atomy uhlíku purinového skeletu. Orientace těchto složek v rámci molekuly byly vypočteny s využitím DFT metod. Výsledky pro jednotlivé izomery byly srovnány a rozdíly popsány. |
| Links | |
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| LC06030, research and development project | Name: Biomolekulární centrum |
| Investor: Ministry of Education, Youth and Sports of the CR, Biomolecular centre | |
| MSM0021622413, plan (intention) | Name: Proteiny v metabolismu a při interakci organismů s prostředím |
| Investor: Ministry of Education, Youth and Sports of the CR, Proteins in metabolism and interaction of organisms with the environment | |
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