J 2008

Optical Property Changes in Low-k Films upon Ultraviolet-Assisted Curing

ESLAVA, Salvador, Guillaume EYMERY, Přemysl MARŠÍK, Francesca IACOPI, Christine KIRSCHHOCK et. al.

Basic information

Original name

Optical Property Changes in Low-k Films upon Ultraviolet-Assisted Curing

Name in Czech

Změny optických vlastností low-k filmů v průběhu UV kůry

Authors

ESLAVA, Salvador (724 Spain), Guillaume EYMERY (250 France), Přemysl MARŠÍK (203 Czech Republic, guarantor), Francesca IACOPI (380 Italy), Christine KIRSCHHOCK (56 Belgium), Karen MAEX (56 Belgium), Johan MARTENS (56 Belgium) and Mikhail BAKLANOV (56 Belgium)

Edition

Journal of the electrochemical society, New York, The Electrochemical Society, 2008, 0013-4651

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10302 Condensed matter physics

Country of publisher

Belgium

Confidentiality degree

není předmětem státního či obchodního tajemství

Impact factor

Impact factor: 2.437

RIV identification code

RIV/00216224:14310/08:00026015

Organization unit

Faculty of Science

UT WoS

000254779700057

Keywords in English

low-k; ellipsometry; UV-cure

Tags

International impact, Reviewed
Změněno: 9/7/2009 09:58, Mgr. Přemysl Maršík, Ph.D.

Abstract

V originále

Ultraviolet-assisted curing (UV curing) has been recently applied to enhance the mechanical properties of low-k films. Knowledge about which ultraviolet energies are most effective is still limited and the consequences of applying the UV-curing process to integrated stacks in on-chip interconnects unknown. To clarify these open questions we investigated the optical properties of a SiCOH low-k layer by purged ultraviolet spectroscopic ellipsometry in the energy region 2-9 eV. The complex refractive index of the low-k film shows an absorption edge with a superimposed absorption band at 6.4 eV that vanishes upon ultraviolet-assisted curing. Comparison with Fourier transform infrared transmission demonstrates that the absorption at 6.4 eV must be attributed to the organic porogens, which have also influences on the absorption edge.

In Czech

Ultraviolet-assisted curing (UV curing) has been recently applied to enhance the mechanical properties of low-k films. Knowledge about which ultraviolet energies are most effective is still limited and the consequences of applying the UV-curing process to integrated stacks in on-chip interconnects unknown. To clarify these open questions we investigated the optical properties of a SiCOH low-k layer by purged ultraviolet spectroscopic ellipsometry in the energy region 2-9 eV. The complex refractive index of the low-k film shows an absorption edge with a superimposed absorption band at 6.4 eV that vanishes upon ultraviolet-assisted curing. Comparison with Fourier transform infrared transmission demonstrates that the absorption at 6.4 eV must be attributed to the organic porogens, which have also influences on the absorption edge.

Links

MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures