Detailed Information on Publication Record
2008
Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation
PREISLER, Jan, Ondřej PEŠ, Pavla FOLTYNOVÁ, Radek VYHNÁNEK, Tomáš VACULOVIČ et. al.Basic information
Original name
Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation
Name in Czech
Off-Line Coupling of Capillary Electrophoresis to Laser Ablation Inductively Coupled Plasma Mass Spectrometry for Elemental Speciation
Authors
PREISLER, Jan (203 Czech Republic, guarantor, belonging to the institution), Ondřej PEŠ (203 Czech Republic, belonging to the institution), Pavla FOLTYNOVÁ (203 Czech Republic, belonging to the institution), Radek VYHNÁNEK (203 Czech Republic, belonging to the institution), Tomáš VACULOVIČ (203 Czech Republic, belonging to the institution) and Viktor KANICKÝ (203 Czech Republic, belonging to the institution)
Edition
Denver, USA, Proceedings of 56th ASMS Conference, 2008
Publisher
ASMS
Other information
Language
English
Type of outcome
Audiovizuální tvorba
Field of Study
10406 Analytical chemistry
Country of publisher
United States of America
Confidentiality degree
není předmětem státního či obchodního tajemství
RIV identification code
RIV/00216224:14310/08:00026062
Organization unit
Faculty of Science
Keywords in English
Electrophoresis Capillary; Elemental Analysis; Laser Ablation; Mass Spectrometry; Inductively Coupled Plasma; Speciation
Tags
Tags
International impact
Změněno: 9/4/2013 12:42, prof. Mgr. Jan Preisler, Ph.D.
V originále
On-line coupling of column separation techniques with inductively coupled plasma optical emission/mass spectrometry (ICP OES/MS) is routinely used for sensitive, element-selective analysis. Direct linking to ICP usually relies on a nebulizer, which often suffers from reduced separation resolution due to induced liquid flow. Here we report first off-line coupling of capillary electrophoresis (CE) with ICP MS, which is based on eluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations, such as capillary electrophoresis or nano liquid chromatography, in terms of both sensitivity and resolution. Furthermore, the fractions collected on the target can be archived and analyzed using other techniques, e.g. MALDI MS or laser-induced fluorescence.
In Czech
On-line coupling of column separation techniques with inductively coupled plasma optical emission/mass spectrometry (ICP OES/MS) is routinely used for sensitive, element-selective analysis. Direct linking to ICP usually relies on a nebulizer, which often suffers from reduced separation resolution due to induced liquid flow. Here we report first off-line coupling of capillary electrophoresis (CE) with ICP MS, which is based on eluent deposition on a suitable target followed by laser ablation (LA) and transfer into ICP. The technique is compatible with microcolumn separations, such as capillary electrophoresis or nano liquid chromatography, in terms of both sensitivity and resolution. Furthermore, the fractions collected on the target can be archived and analyzed using other techniques, e.g. MALDI MS or laser-induced fluorescence.
Links
| LC06035, research and development project |
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| MSM0021622411, plan (intention) |
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| MSM0021622412, plan (intention) |
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| MSM0021622415, plan (intention) |
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