GC-ICP-MS technique for speciation of organotin compounds

MACHÁT, Jiří, Veronika PEŠKOVÁ and Eva NIEDOBOVÁ. GC-ICP-MS technique for speciation of organotin compounds. In XIXth Slovak-Czech Spectroscopic Conference. 2008. ISBN 978-80-223-2557-8.

Basic information

• Original name: GC-ICP-MS technique for speciation of organotin compounds
• Name in Czech: GC-ICP-MS technika pro stanoveni organospecií cínu
• Authors: MACHÁT, Jiří (203 Czech Republic, guarantor, belonging to the institution), Veronika PEŠKOVÁ (203 Czech Republic, belonging to the institution) and Eva NIEDOBOVÁ (203 Czech Republic).
• Edition: XIXth Slovak-Czech Spectroscopic Conference, 2008.

Other information

• Original language: English
• Type of outcome: Conference abstract
• Field of Study: 10406 Analytical chemistry
• Country of publisher: Slovakia
• Confidentiality degree: is not subject to a state or trade secret
• RIV identification code: RIV/00216224:14310/08:00026613
• Organization unit: Faculty of Science
• ISBN: 978-80-223-2557-8
• Keywords in English: GC; ICP-MS; speciation; tin
• Tags: GC, ICP-MS, Speciation, TiN
• Tags: International impact

Abstract

Organotin compounds were widely used as pesticides, polyvinylchloride stabilizers and in other branches. As a result these compounds can be found in different areas of the environment. Because of their toxicological properties the contact of these compounds with non-target organisms should be avoided and suitable analytical techniques must be available for investigating their content in different environmental samples. Organotin compounds can be determined in various matrices using separation technique hyphenated to element specific detection. In this work gas chromatography with inductively coupled plasma mass spectrometry detection (GC-ICP-MS) were applied for determination of mono-, di- and tri-butyltin compounds in wood. The influence of basic detector parameters was studied as well as suitable sample preparation step. Different extraction strategies were tested and their efficiency compared. Method was applied to analysis of wood samples preserved by tributyltin-oxid based fungicide.

Abstract (in Czech)

V práci je popsáno využití kombinované techniky plynové chromatografie s detekcí hmotnostní spektrometrií s indukčně vázaným plazmatem pro stanovení butylcíničitých sloučenin ve vzorku dřeva, ošetřeného fungicidem na bázi tributylcín-oxidu.

Links

• MSM0021622412, plan (intention): Name: Interakce mezi chemickými látkami, prostředím a biologickými systémy a jejich důsledky na globální, regionální a lokální úrovni (INCHEMBIOL) (Acronym: INCHEMBIOL)

Investor: Ministry of Education, Youth and Sports of the CR, Interactions among the chemicals, environment and biological systems and their consequences on the global, regional and local scales (INCHEMBIOL)