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@inproceedings{815591,
author = {Kadeřávek, Pavel and Fiala, Radovan},
address = {Brno},
booktitle = {23rd NMR Valtice},
edition = {1},
keywords = {dynamics; NMR spectroscopy; nucleic acid; relaxation; chemical shift anisotropy},
language = {eng},
location = {Brno},
isbn = {978-80-86441-39-9},
pages = {31-31},
publisher = {Masarykova Univerzita},
title = {C-13 Relaxation Study of RNA Dynamics: Application to UUCG Hairpin Loop},
year = {2008}
}
TY - JOUR
ID - 815591
AU - Kadeřávek, Pavel - Fiala, Radovan
PY - 2008
TI - C-13 Relaxation Study of RNA Dynamics: Application to UUCG Hairpin Loop
PB - Masarykova Univerzita
CY - Brno
SN - 9788086441399
KW - dynamics
KW - NMR spectroscopy
KW - nucleic acid
KW - relaxation
KW - chemical shift anisotropy
N2 - The Model-free procedure to analyze NMR relaxation rates in terms of intramolecular motions was modified to explicitly take into account asymmetric character of the carbon chemical shielding tensors. The effect of using the improved procedure was studied on a 14-nt RNA hairpin including UUCG tetraloop. Spin-spin and spin-lattice relaxation rates were measured for all protonated base and C1’ carbons at 600 MHz and 500 MHz and the values of carbon-hydrogen heteronuclear NOE were obtained for purine C8 and adenine C2 carbons. The results of the Model free analysis using the extended version of the Relax program was compared to the result produced by the standard version of the program as well as to the published data.
ER -
KADEŘÁVEK, Pavel and Radovan FIALA. C-13 Relaxation Study of RNA Dynamics: Application to UUCG Hairpin Loop. In \textit{23rd NMR Valtice}. 1st ed. Brno: Masarykova Univerzita, 2008, p.~31-31. ISBN~978-80-86441-39-9.
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