The interpretation of the DSC signals of the lead-free solder alloy systems using the CALPHAD approach

SOPOUŠEK, Jiří and Marian PALCUT. The interpretation of the DSC signals of the lead-free solder alloy systems using the CALPHAD approach. In CALPHAD XXXVIII (May 17-22, 2009). 2009.

Basic information

• Original name: The interpretation of the DSC signals of the lead-free solder alloy systems using the CALPHAD approach
• Name in Czech: Interpretace DSC signálů pájek bez olova za použití metody CALPHAD
• Name (in English): The interpretation of the DSC signals of the lead-free solder alloy systems using the CALPHAD approach
• Authors: SOPOUŠEK, Jiří (203 Czech Republic, guarantor, belonging to the institution) and Marian PALCUT (703 Slovakia).
• Edition: CALPHAD XXXVIII (May 17-22, 2009), 2009.

Other information

• Original language: Czech
• Type of outcome: Conference abstract
• Field of Study: 10403 Physical chemistry
• Country of publisher: Slovakia
• Confidentiality degree: is not subject to a state or trade secret
• RIV identification code: RIV/00216224:14310/09:00051152
• Organization unit: Faculty of Science
• Keywords (in Czech): CALPHAD; termická analýza; bez olova; fázové diagramy
• Keywords in English: CALPHAD; thermal analysis; lead-free; phase diagram
• Tags: CALPHAD, IK, lead-free, Phase diagram, rivok, Thermal analysis
• Tags: International impact

Abstract

The knowledge of the phase diagrams and the predictions of the respective liquidus and solidus temperatures are of a great importance. In the present study, the heat flow differential scanning calorimetry (DSC) was used to describe the phase transformations in the lead-free solder systems Sn-Ag-Cu and Sn-Ag-Cu-X (X=Bi, In). We used the Neztsch STA CD/3/403/5/G instrument that enables for the detection of the DSC signal using the heating and cooling rates of down to 0.1 K/min. At these conditions, the samples could be considered to be in the state close to the thermodynamic equilibrium. The DSC heating signal of the materials consisted of two or more different overlapping peaks resulting from the precipitation of secondary phases. The equilibrium state calculations were performed using the CALPHAD approach. The individual phases and their molar Gibbs energies were described by the parameters taken from the COST531 Thermodynamic Database of Lead-free Solders [1]. Since the CALPHAD approach allows for the calculation of thermodynamic functions, the experimental DSC curves could be simulated using the calculated molar enthalpies of the solders (deltaH). The standard molar enthalpies were calculated for different temperatures and for the various lead-free alloys. The respective temperature derivatives were directly and successfully compared with the experimental DSC curves.

Abstract (in English)

The knowledge of the phase diagrams and the predictions of the respective liquidus and solidus temperatures are of a great importance. In the present study, the heat flow differential scanning calorimetry (DSC) was used to describe the phase transformations in the lead-free solder systems Sn-Ag-Cu and Sn-Ag-Cu-X (X=Bi, In). We used the Neztsch STA CD/3/403/5/G instrument that enables for the detection of the DSC signal using the heating and cooling rates of down to 0.1 K/min. At these conditions, the samples could be considered to be in the state close to the thermodynamic equilibrium. The DSC heating signal of the materials consisted of two or more different overlapping peaks resulting from the precipitation of secondary phases. The equilibrium state calculations were performed using the CALPHAD approach. The individual phases and their molar Gibbs energies were described by the parameters taken from the COST531 Thermodynamic Database of Lead-free Solders [1]. Since the CALPHAD approach allows for the calculation of thermodynamic functions, the experimental DSC curves could be simulated using the calculated molar enthalpies of the solders (deltaH). The standard molar enthalpies were calculated for different temperatures and for the various lead-free alloys. The respective temperature derivatives were directly and successfully compared with the experimental DSC curves.

Links

• MSM0021622410, plan (intention): Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur

Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures

• OC09010, research and development project: Name: Studium termodynamických vlastností a fázových diagramů soustav pro vysokoteplotní bezolovnaté pájky

Investor: Ministry of Education, Youth and Sports of the CR, Thermodynamic and Phase Diagram Studies of Systems for High Temperature Lead-Free Solders