a 2009

Experimental determination of phase equilibria and reassessment of Ag-Pd system

ZEMANOVÁ, Adéla, Jiří SOPOUŠEK and Jan VŘEŠŤÁL

Basic information

Original name

Experimental determination of phase equilibria and reassessment of Ag-Pd system

Name in Czech

Experimantální stanovení fázových rovnováh a reassessment soustavy Ag-Pd

Name (in English)

Experimental determination of phase equilibria and reassessment of Ag-Pd system

Authors

ZEMANOVÁ, Adéla (203 Czech Republic), Jiří SOPOUŠEK (203 Czech Republic, guarantor, belonging to the institution) and Jan VŘEŠŤÁL (203 Czech Republic, belonging to the institution)

Edition

CALPHAD XXXVIII (May 17-22, 2009), 2009

Other information

Language

Czech

Type of outcome

Konferenční abstrakt

Field of Study

10403 Physical chemistry

Country of publisher

Slovakia

Confidentiality degree

není předmětem státního či obchodního tajemství

RIV identification code

RIV/00216224:14310/09:00051154

Organization unit

Faculty of Science

UT WoS

000281019900034

Keywords (in Czech)

CALPHAD; termická analýza; fázové diagramy

Keywords in English

CALPHAD; thermal analysis; phase diagram

Tags

International impact
Změněno: 7/2/2012 09:12, prof. RNDr. Jiří Sopoušek, CSc.

Abstract

V originále

In lead-free soldering, the silver is usually used as solder component and palladium often as component of substrate. Therefore, Ag-Pd system is of interest for possible interference of components in solder joints. The system Ag-Pd reveals simple liquidus-solidus two phase region [1]. An enthalpy of mixing of liquid Ag-Pd solution was evaluated recently [2]. In this work an additional DSC determination of solidus and liquidus temperatures at chosen compositions was performed. Existing assessment [1] of thermodynamic and phase equilibrium data in the Ag-Pd system was revised on the base of calorimetric data for liquid Ag-Pd alloys [2] and DSC measurement. New determination of liquidus and solidus temperatures using DSC method in this work confirmed substantially narrower liquid/fcc two-phase field in phase diagram, in agreement with the reassessment.

In English

In lead-free soldering, the silver is usually used as solder component and palladium often as component of substrate. Therefore, Ag-Pd system is of interest for possible interference of components in solder joints. The system Ag-Pd reveals simple liquidus-solidus two phase region [1]. An enthalpy of mixing of liquid Ag-Pd solution was evaluated recently [2]. In this work an additional DSC determination of solidus and liquidus temperatures at chosen compositions was performed. Existing assessment [1] of thermodynamic and phase equilibrium data in the Ag-Pd system was revised on the base of calorimetric data for liquid Ag-Pd alloys [2] and DSC measurement. New determination of liquidus and solidus temperatures using DSC method in this work confirmed substantially narrower liquid/fcc two-phase field in phase diagram, in agreement with the reassessment.

Links

MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures
OC09010, research and development project
Name: Studium termodynamických vlastností a fázových diagramů soustav pro vysokoteplotní bezolovnaté pájky
Investor: Ministry of Education, Youth and Sports of the CR, Thermodynamic and Phase Diagram Studies of Systems for High Temperature Lead-Free Solders