Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies

SVOBODOVÁ, Ivona, Jana HAVLÍČKOVÁ, Jan PLUTNAR, Přemysl LUBAL, Jan KOTEK and Petr HERMANN. Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies. Eur. J. Inorg. Chem. Germany: Wiley-VCH Verlag GMBH, 2009, vol. 2009, No 24, p. 3577-3592. ISSN 1434-1948.

Basic information

• Original name: Metal Complexes of 4,11-Dimethyl-1,4,8,11-tetraazacyclotetradecane-1,8-bis(methylphosphonic acid) - Thermodynamic and Formation/Decomplexation Kinetic Studies
• Name in Czech: Komplexy 4,11-dimethyl-1,4,8,11-tetraazacyklotetradekan-1,8-bis(fosfonové kyseliny) s ionty kovů - termodynamické studium a studiumformační/dekomplexační kinetiky.
• Authors: SVOBODOVÁ, Ivona (203 Czech Republic), Jana HAVLÍČKOVÁ (203 Czech Republic), Jan PLUTNAR (203 Czech Republic), Přemysl LUBAL (203 Czech Republic), Jan KOTEK (203 Czech Republic) and Petr HERMANN (203 Czech Republic, guarantor).
• Edition: Eur. J. Inorg. Chem. Germany, Wiley-VCH Verlag GMBH, 2009, 1434-1948.

Other information

• Original language: English
• Type of outcome: Article in a journal
• Field of Study: 10402 Inorganic and nuclear chemistry
• Country of publisher: Germany
• Confidentiality degree: is not subject to a state or trade secret
• WWW: URL
• Impact factor: Impact factor: 2.941
• RIV identification code: RIV/00216224:14310/09:00037426
• Organization unit: Faculty of Science
• UT WoS: 000269395800008
• Keywords (in Czech): Krystalové structury; makrocyklické ligandy; fosfonové komplexy; komplexy Cu(ii); deriváty cyklamu; komplex Zn(ii); komplexy Cd(ii); complexation / decomplexation kinetics; radiopharmaceuticals
• Keywords in English: X-ray crystal structure; macrocyclic ligands; phosphonate complexes; copper(ii) complexes; cyclam derivatives; zinc(ii) complexes; cadmium(ii) complexes; complexation / decomplexation kinetics; radiopharmaceuticals
• Tags: International impact, Reviewed

Abstract

Bis(phosphonic) acid derivative of cyclam was synthesized by an improved synthesis. Thermodynamic stability of divalent metal complexes was determined. Formation and decomplexation kinetics of complexes with divalent copper, zinc and cadmium was investigated.

Abstract (in Czech)

Bis(fosfonový) derivát cyklamu byl připraven vylepšenou syntézou. Byla určena termodynamická stabilita komplexů s dvojmocnými ionty kovů. Byla zkoumána formační a dekomplexační kinetika komplexů s dvojmocnými ionty kovů (měď, zinek a kadmium).

Links

• ME09065, research and development project: Name: Výzkum nových detekčních systémů na bázi senzorových polí pro použití ve speciační analýze

Investor: Ministry of Education, Youth and Sports of the CR, Research of new detection systems based on sensor arrays for application in speciation analysis, Research and Development Programme KONTAKT (ME)

• OC 179, research and development project: Name: Molekulární zobrazování založené na systémech obsahujících kovy.