J 2009

The first crystallographic observation of up to the third hydration layer of Cu(II) ion in an unusual 'water-cation layer' templated by an Anderson polyoxometallate

ALI, M., D. DUTTA, S. BISWAS, Jaromír MAREK, A. D. JANA et. al.

Basic information

Original name

The first crystallographic observation of up to the third hydration layer of Cu(II) ion in an unusual 'water-cation layer' templated by an Anderson polyoxometallate

Name in Czech

První krystalografické pozorování 3. hydratační vrstvy kolem měďnatého iontu v neobvyklé vrstvě "voda-kationt" formované Anderson polyoxometaláty

Authors

ALI, M. (356 India), D. DUTTA (356 India), S. BISWAS (356 India), Jaromír MAREK (203 Czech Republic, guarantor, belonging to the institution) and A. D. JANA (356 India)

Edition

CRYSTENGCOMM, Cambridge, UK, RSC Publishing, 2009, 1466-8033

Other information

Language

English

Type of outcome

Článek v odborném periodiku

Field of Study

10402 Inorganic and nuclear chemistry

Country of publisher

United Kingdom of Great Britain and Northern Ireland

Confidentiality degree

není předmětem státního či obchodního tajemství

References:

Impact factor

Impact factor: 4.183

RIV identification code

RIV/00216224:14310/09:00038650

Organization unit

Faculty of Science

UT WoS

000271864700016

Keywords (in Czech)

supramolekulární struktura; měď; vodíková vazba

Keywords in English

hydration; copper; hydrogen bond; supramolecular structure
Změněno: 2/5/2012 13:09, doc. RNDr. Jaromír Marek, Ph.D.

Abstract

ORIG CZ

V originále

This constitutes the first crystallographic observation of hydrated Cu(II) ion retaining up to its third hydration layer which, along with the chair form water hexamer, builds up a unique water - cation layer. Moreover, an unprecedented supramolecular honeycomb network of [Cu(phen)3]2+ units templated by Anderson polyoxometallate units occupy the intervening spaces between successive water layers.

In Czech

Článek popisuje krystalovou strukturu komplexu s neobvyklou 3. hydratační vrstvou kolem měďnatého iontu.

Links

MSM0021622410, plan (intention)
Name: Fyzikální a chemické vlastnosti pokročilých materiálů a struktur
Investor: Ministry of Education, Youth and Sports of the CR, Physical and chemical properties of advanced materials and structures